TY - JOUR
T1 - Thermodynamically stable Si wC xN yO z polymer-like, amorphous ceramics made from organic precursors
AU - Morcos, Riham M.
AU - Navrotsky, Alexandra
AU - Varga, Tamas
AU - Ahn, Dongjoon
AU - Saha, Atanu
AU - Poli, Fabrizia
AU - Müller, Klaus
AU - Raj, Rishi
N1 - Copyright:
Copyright 2012 Elsevier B.V., All rights reserved.
PY - 2008/7
Y1 - 2008/7
N2 - This communication reports new results on the enthalpy of formation of pseudo-amorphous ceramic compounds constituted from silicon, carbon, oxygen, and nitrogen (SiCNO), made from the polymer route. Again, like the SiCO materials, although with one exception, the enthalpy of formation from crystalline components (SiO 2 cristobalite, β-Si 3N 4, SiC, and excess C) is negative. Some of the alloyed oxygen-nitrogen compositions yield enthalpies that are much more negative (̃100 kJ/g . atom) in comparison with compositions that contain mainly oxygen or nitrogen (̃20 kJ/g×atom). The exception, having a N/O ratio near 2, has a positive value for the enthalpy. This may reflect the presence of nanoclusters of stoichiometric Si 2N 2O instead of the pseudo-amorphous nanodomain structure seen for the other samples.
AB - This communication reports new results on the enthalpy of formation of pseudo-amorphous ceramic compounds constituted from silicon, carbon, oxygen, and nitrogen (SiCNO), made from the polymer route. Again, like the SiCO materials, although with one exception, the enthalpy of formation from crystalline components (SiO 2 cristobalite, β-Si 3N 4, SiC, and excess C) is negative. Some of the alloyed oxygen-nitrogen compositions yield enthalpies that are much more negative (̃100 kJ/g . atom) in comparison with compositions that contain mainly oxygen or nitrogen (̃20 kJ/g×atom). The exception, having a N/O ratio near 2, has a positive value for the enthalpy. This may reflect the presence of nanoclusters of stoichiometric Si 2N 2O instead of the pseudo-amorphous nanodomain structure seen for the other samples.
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U2 - 10.1111/j.1551-2916.2008.02427.x
DO - 10.1111/j.1551-2916.2008.02427.x
M3 - Article
AN - SCOPUS:53349150258
SN - 0002-7820
VL - 91
SP - 2391
EP - 2393
JO - Journal of the American Ceramic Society
JF - Journal of the American Ceramic Society
IS - 7
ER -