The Zeeman effect in the [17.6]7.5-X 18.5 transition of holmium monoxide

C. Linton; Timothy Steimle; H. Wang

doi:10.1016/j.jms.2012.04.009

The Zeeman effect in the [17.6]7.5-X ₁8.5 transition of holmium monoxide

C. Linton, Timothy Steimle, H. Wang

Molecular Sciences, School of (SMS)

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

The high resolution molecular beam laser induced fluorescence (LIF) spectrum of the (0, 0) band of the [17.6]7.5-X ₁8.5 system of holmium monoxide, HoO, has been recorded field free and in the presence of a variable magnetic field. The Zeeman shifts and splittings in the LIF spectra of several hyperfine lines of the R(8.5) and P(8.5) transitions were analyzed to produce values for the magnitude of the effective magnetic g-factors, g _eff, of 9.86(2), 10.04(2) and 11.04(2) for [17.6]7.5, v = 0, J = 7.5 and 9.5 and X ₁8.5, v = 0, J = 8.5 respectively. Comparison with calculated values of g _eff indicated that, in a Hund's case (a) description, the transition was primarily ⁶H _7.5- ⁶I _8.5.

Original language	English (US)
Pages (from-to)	15-20
Number of pages	6
Journal	Journal of molecular spectroscopy
Volume	275
Issue number	1
DOIs	https://doi.org/10.1016/j.jms.2012.04.009
State	Published - May 2012

Keywords

High resolution spectroscopy
Holmium monoxide
Hyperfine structure
Laser-induced fluorescence
Zeeman effect

ASJC Scopus subject areas

Atomic and Molecular Physics, and Optics
Spectroscopy
Physical and Theoretical Chemistry

Access to Document

10.1016/j.jms.2012.04.009

Cite this

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title = "The Zeeman effect in the [17.6]7.5-X 18.5 transition of holmium monoxide",

abstract = "The high resolution molecular beam laser induced fluorescence (LIF) spectrum of the (0, 0) band of the [17.6]7.5-X 18.5 system of holmium monoxide, HoO, has been recorded field free and in the presence of a variable magnetic field. The Zeeman shifts and splittings in the LIF spectra of several hyperfine lines of the R(8.5) and P(8.5) transitions were analyzed to produce values for the magnitude of the effective magnetic g-factors, g eff, of 9.86(2), 10.04(2) and 11.04(2) for [17.6]7.5, v = 0, J = 7.5 and 9.5 and X 18.5, v = 0, J = 8.5 respectively. Comparison with calculated values of g eff indicated that, in a Hund's case (a) description, the transition was primarily 6H 7.5- 6I 8.5.",

keywords = "High resolution spectroscopy, Holmium monoxide, Hyperfine structure, Laser-induced fluorescence, Zeeman effect",

author = "C. Linton and Timothy Steimle and H. Wang",

note = "Funding Information: This research at Arizona State University has been supported by a grant from the Fundamental Interactions Branch, Division of Chemical Sciences, Office of Basic Energy Sciences, Department of Energy (DE-FG02-01ER15153-A003). ",

year = "2012",

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doi = "10.1016/j.jms.2012.04.009",

language = "English (US)",

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T1 - The Zeeman effect in the [17.6]7.5-X 18.5 transition of holmium monoxide

AU - Linton, C.

AU - Steimle, Timothy

AU - Wang, H.

N1 - Funding Information: This research at Arizona State University has been supported by a grant from the Fundamental Interactions Branch, Division of Chemical Sciences, Office of Basic Energy Sciences, Department of Energy (DE-FG02-01ER15153-A003).

PY - 2012/5

Y1 - 2012/5

N2 - The high resolution molecular beam laser induced fluorescence (LIF) spectrum of the (0, 0) band of the [17.6]7.5-X 18.5 system of holmium monoxide, HoO, has been recorded field free and in the presence of a variable magnetic field. The Zeeman shifts and splittings in the LIF spectra of several hyperfine lines of the R(8.5) and P(8.5) transitions were analyzed to produce values for the magnitude of the effective magnetic g-factors, g eff, of 9.86(2), 10.04(2) and 11.04(2) for [17.6]7.5, v = 0, J = 7.5 and 9.5 and X 18.5, v = 0, J = 8.5 respectively. Comparison with calculated values of g eff indicated that, in a Hund's case (a) description, the transition was primarily 6H 7.5- 6I 8.5.

AB - The high resolution molecular beam laser induced fluorescence (LIF) spectrum of the (0, 0) band of the [17.6]7.5-X 18.5 system of holmium monoxide, HoO, has been recorded field free and in the presence of a variable magnetic field. The Zeeman shifts and splittings in the LIF spectra of several hyperfine lines of the R(8.5) and P(8.5) transitions were analyzed to produce values for the magnitude of the effective magnetic g-factors, g eff, of 9.86(2), 10.04(2) and 11.04(2) for [17.6]7.5, v = 0, J = 7.5 and 9.5 and X 18.5, v = 0, J = 8.5 respectively. Comparison with calculated values of g eff indicated that, in a Hund's case (a) description, the transition was primarily 6H 7.5- 6I 8.5.

KW - High resolution spectroscopy

KW - Holmium monoxide

KW - Hyperfine structure

KW - Laser-induced fluorescence

KW - Zeeman effect

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