TY - JOUR
T1 - The structure of Mn-rich tuperssuatsiaite
T2 - A palygorskite-related mineral
AU - Cámara, Fernando
AU - Garvie, Laurence
AU - Devouard Bertrand, B.
AU - Groy, Thomas L.
AU - Buseck, P R
PY - 2002/10
Y1 - 2002/10
N2 - The structure of tuperssuatsiaite from the Aris phonolite in central Namibia was refined to an R index of 0.075 for 905 observed reflections [I > 2σ(I)] obtained with a four-circle X-ray diffractometer. Tuperssuatsiaite is monoclinic, C2/m, with a = 14.034(7), b = 17.841(7), c = 5.265(2) Å, and β = 103.67(4)°. Microprobe analysis gave an average composition of Na1.87Fe2.14Mn0.48 palygorskite Mg5[Si8O20](OH)2-H2O. Tuperssuatsiaite consists of ribbons of SiO4 tetrahedra linked by bands of octahedra running parallel to c. Channels occur that could be occupied by H2O as in palygorskite. The octahedral band contains three edge-sharing, six-coordinated sites labeled M1, M2, and M3. This band consists of alternating M3-M1-M3 and M2-M2 octahedra along [001]. The M1 and M2 sites both contain Fe and Mn, and M3 is occupied by Na. Bondvalence calculations indicate a formal charge of 2.48 for M1 and 2.67 for M2, i.e., a charge distribution of 2R3+:1R2+. Octahedral angle variance and volume are similar for both sites, indicating disorder in the distribution of Fe and Mn atoms between the sites. Charge balance requirements agree with the presence of Fe3+ and Mn2+.
AB - The structure of tuperssuatsiaite from the Aris phonolite in central Namibia was refined to an R index of 0.075 for 905 observed reflections [I > 2σ(I)] obtained with a four-circle X-ray diffractometer. Tuperssuatsiaite is monoclinic, C2/m, with a = 14.034(7), b = 17.841(7), c = 5.265(2) Å, and β = 103.67(4)°. Microprobe analysis gave an average composition of Na1.87Fe2.14Mn0.48 palygorskite Mg5[Si8O20](OH)2-H2O. Tuperssuatsiaite consists of ribbons of SiO4 tetrahedra linked by bands of octahedra running parallel to c. Channels occur that could be occupied by H2O as in palygorskite. The octahedral band contains three edge-sharing, six-coordinated sites labeled M1, M2, and M3. This band consists of alternating M3-M1-M3 and M2-M2 octahedra along [001]. The M1 and M2 sites both contain Fe and Mn, and M3 is occupied by Na. Bondvalence calculations indicate a formal charge of 2.48 for M1 and 2.67 for M2, i.e., a charge distribution of 2R3+:1R2+. Octahedral angle variance and volume are similar for both sites, indicating disorder in the distribution of Fe and Mn atoms between the sites. Charge balance requirements agree with the presence of Fe3+ and Mn2+.
UR - http://www.scopus.com/inward/record.url?scp=0036811390&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0036811390&partnerID=8YFLogxK
U2 - 10.2138/am-2002-1023
DO - 10.2138/am-2002-1023
M3 - Article
AN - SCOPUS:0036811390
SN - 0003-004X
VL - 87
SP - 1458
EP - 1463
JO - American Mineralogist
JF - American Mineralogist
IS - 10
ER -