The permanent electric dipole moments of calcium monohydride, CaH

Timothy Steimle, Jinhai Chen, Jamie Gengler

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24 Scopus citations

Abstract

The study of permanent electric dipole moments of alkaline earth monohalides was analyzed using optical Stark spectroscopy. Investigations show that the decrease in μ upon excitation to the A 2II state was consistent with alkaline earth monovalent molecules. The appearance of electric-field-induced transitions in the high resolution laser-induced fluorescence spectra was also analyzed to produce values of the permanent electric dipole moments. The results show that error in μ(X 2σ +) could be reduced in an optical Stark study of CaD.

Original languageEnglish (US)
Pages (from-to)829-834
Number of pages6
JournalJournal of Chemical Physics
Volume121
Issue number2
DOIs
StatePublished - Jul 8 2004

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ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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