The permanent electric dipole moments of calcium monohydride, CaH

Timothy Steimle, Jinhai Chen, Jamie Gengler

Research output: Contribution to journalArticle

22 Citations (Scopus)

Abstract

The study of permanent electric dipole moments of alkaline earth monohalides was analyzed using optical Stark spectroscopy. Investigations show that the decrease in μ upon excitation to the A 2II state was consistent with alkaline earth monovalent molecules. The appearance of electric-field-induced transitions in the high resolution laser-induced fluorescence spectra was also analyzed to produce values of the permanent electric dipole moments. The results show that error in μ(X 2σ +) could be reduced in an optical Stark study of CaD.

Original languageEnglish (US)
Pages (from-to)829-834
Number of pages6
JournalJournal of Chemical Physics
Volume121
Issue number2
DOIs
StatePublished - Jul 8 2004

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Electric dipole moments
electric moments
electric dipoles
calcium
dipole moments
Earth (planet)
Calcium
laser induced fluorescence
Fluorescence
Electric fields
Spectroscopy
Molecules
electric fields
Lasers
high resolution
spectroscopy
excitation
molecules

ASJC Scopus subject areas

  • Atomic and Molecular Physics, and Optics

Cite this

The permanent electric dipole moments of calcium monohydride, CaH. / Steimle, Timothy; Chen, Jinhai; Gengler, Jamie.

In: Journal of Chemical Physics, Vol. 121, No. 2, 08.07.2004, p. 829-834.

Research output: Contribution to journalArticle

Steimle, Timothy ; Chen, Jinhai ; Gengler, Jamie. / The permanent electric dipole moments of calcium monohydride, CaH. In: Journal of Chemical Physics. 2004 ; Vol. 121, No. 2. pp. 829-834.
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