Abstract
The 11.9Ω 32 ← X 2Π 32(0,0) and (1,0) bands of platinum monofluoride, PtF, have been recorded field-free and in the presence of a static electric field. The 19F(I 12) and 195Pt(I 12) magnetic hyperfine interactions have been analyzed and compared with predicted values obtained using atomic information and a proposed molecular orbital correlation diagram. The optical Stark shifts were analyzed to produce the permanent electric dipole moments, μCombining right arrow abovee l, of 2.47(11)D and 3.42(6)D for the 11.9Ω 32 and X 2Π 32states, respectively. The observed trend in μCombining right arrow abovee l for the PtX (X C,N,O,S and F) series is discussed and a comparison with IrF made.
| Original language | English (US) |
|---|---|
| Article number | 054309 |
| Journal | Journal of Chemical Physics |
| Volume | 137 |
| Issue number | 5 |
| DOIs | |
| State | Published - Aug 7 2012 |
Fingerprint
ASJC Scopus subject areas
- Physics and Astronomy(all)
- Physical and Theoretical Chemistry
- Medicine(all)
Cite this
The permanent electric dipole moment and hyperfine interactions in platinum monofluoride, PtF. / Qin, Chengbing; Zhang, Ruohan; Wang, Fang; Steimle, Timothy.
In: Journal of Chemical Physics, Vol. 137, No. 5, 054309, 07.08.2012.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - The permanent electric dipole moment and hyperfine interactions in platinum monofluoride, PtF
AU - Qin, Chengbing
AU - Zhang, Ruohan
AU - Wang, Fang
AU - Steimle, Timothy
PY - 2012/8/7
Y1 - 2012/8/7
N2 - The 11.9Ω 32 ← X 2Π 32(0,0) and (1,0) bands of platinum monofluoride, PtF, have been recorded field-free and in the presence of a static electric field. The 19F(I 12) and 195Pt(I 12) magnetic hyperfine interactions have been analyzed and compared with predicted values obtained using atomic information and a proposed molecular orbital correlation diagram. The optical Stark shifts were analyzed to produce the permanent electric dipole moments, μCombining right arrow abovee l, of 2.47(11)D and 3.42(6)D for the 11.9Ω 32 and X 2Π 32states, respectively. The observed trend in μCombining right arrow abovee l for the PtX (X C,N,O,S and F) series is discussed and a comparison with IrF made.
AB - The 11.9Ω 32 ← X 2Π 32(0,0) and (1,0) bands of platinum monofluoride, PtF, have been recorded field-free and in the presence of a static electric field. The 19F(I 12) and 195Pt(I 12) magnetic hyperfine interactions have been analyzed and compared with predicted values obtained using atomic information and a proposed molecular orbital correlation diagram. The optical Stark shifts were analyzed to produce the permanent electric dipole moments, μCombining right arrow abovee l, of 2.47(11)D and 3.42(6)D for the 11.9Ω 32 and X 2Π 32states, respectively. The observed trend in μCombining right arrow abovee l for the PtX (X C,N,O,S and F) series is discussed and a comparison with IrF made.
UR - http://www.scopus.com/inward/record.url?scp=84864832628&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84864832628&partnerID=8YFLogxK
U2 - 10.1063/1.4734596
DO - 10.1063/1.4734596
M3 - Article
C2 - 22894350
AN - SCOPUS:84864832628
VL - 137
JO - Journal of Chemical Physics
JF - Journal of Chemical Physics
SN - 0021-9606
IS - 5
M1 - 054309
ER -