The permanent electric dipole moment and hyperfine interactions in platinum monofluoride, PtF

Chengbing Qin; Ruohan Zhang; Fang Wang; Timothy Steimle

doi:10.1063/1.4734596

The permanent electric dipole moment and hyperfine interactions in platinum monofluoride, PtF

Chengbing Qin, Ruohan Zhang, Fang Wang, Timothy Steimle

CLAS-NS: Molecular Sciences, School of (SMS)

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

The 11.9Ω 32 ← X ²Π ₃₂(0,0) and (1,0) bands of platinum monofluoride, PtF, have been recorded field-free and in the presence of a static electric field. The ¹⁹F(I 12) and ¹⁹⁵Pt(I 12) magnetic hyperfine interactions have been analyzed and compared with predicted values obtained using atomic information and a proposed molecular orbital correlation diagram. The optical Stark shifts were analyzed to produce the permanent electric dipole moments, μCombining right arrow abovee l, of 2.47(11)D and 3.42(6)D for the 11.9Ω 32 and X ²Π ₃₂states, respectively. The observed trend in μCombining right arrow abovee l for the PtX (X C,N,O,S and F) series is discussed and a comparison with IrF made.

Original language	English (US)
Article number	054309
Journal	Journal of Chemical Physics
Volume	137
Issue number	5
DOIs	https://doi.org/10.1063/1.4734596
State	Published - Aug 7 2012

ASJC Scopus subject areas

Physics and Astronomy(all)
Physical and Theoretical Chemistry

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title = "The permanent electric dipole moment and hyperfine interactions in platinum monofluoride, PtF",

abstract = "The 11.9Ω 32 ← X 2Π 32(0,0) and (1,0) bands of platinum monofluoride, PtF, have been recorded field-free and in the presence of a static electric field. The 19F(I 12) and 195Pt(I 12) magnetic hyperfine interactions have been analyzed and compared with predicted values obtained using atomic information and a proposed molecular orbital correlation diagram. The optical Stark shifts were analyzed to produce the permanent electric dipole moments, μCombining right arrow abovee l, of 2.47(11)D and 3.42(6)D for the 11.9Ω 32 and X 2Π 32states, respectively. The observed trend in μCombining right arrow abovee l for the PtX (X C,N,O,S and F) series is discussed and a comparison with IrF made.",

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T1 - The permanent electric dipole moment and hyperfine interactions in platinum monofluoride, PtF

AU - Qin, Chengbing

AU - Zhang, Ruohan

AU - Wang, Fang

AU - Steimle, Timothy

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N2 - The 11.9Ω 32 ← X 2Π 32(0,0) and (1,0) bands of platinum monofluoride, PtF, have been recorded field-free and in the presence of a static electric field. The 19F(I 12) and 195Pt(I 12) magnetic hyperfine interactions have been analyzed and compared with predicted values obtained using atomic information and a proposed molecular orbital correlation diagram. The optical Stark shifts were analyzed to produce the permanent electric dipole moments, μCombining right arrow abovee l, of 2.47(11)D and 3.42(6)D for the 11.9Ω 32 and X 2Π 32states, respectively. The observed trend in μCombining right arrow abovee l for the PtX (X C,N,O,S and F) series is discussed and a comparison with IrF made.

AB - The 11.9Ω 32 ← X 2Π 32(0,0) and (1,0) bands of platinum monofluoride, PtF, have been recorded field-free and in the presence of a static electric field. The 19F(I 12) and 195Pt(I 12) magnetic hyperfine interactions have been analyzed and compared with predicted values obtained using atomic information and a proposed molecular orbital correlation diagram. The optical Stark shifts were analyzed to produce the permanent electric dipole moments, μCombining right arrow abovee l, of 2.47(11)D and 3.42(6)D for the 11.9Ω 32 and X 2Π 32states, respectively. The observed trend in μCombining right arrow abovee l for the PtX (X C,N,O,S and F) series is discussed and a comparison with IrF made.

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