Abstract
Lanthanum tantalates are important refractory materials with application in photocatalysis, solid oxide fuel cells, and phosphors. Soft-chemical synthesis utilizing the Lindqvist ion, [Ta6O19]8-, has yielded a new phase, La2Ta2O7(OH)2. Using the hydrated phase as a starting material, a new lanthanum orthotantalate polymorph was formed by heating to 850 °C, which converts to a previously reported LaTaO4 polymorph at 1200 °C. The stabilities of La 2Ta2O7(OH)2 (LaTa-OH), the intermediate LaTaO4 polymorph (LaTa-850), and the high temperature phase (LaTa-1200) were investigated using high-temperature oxide melt solution calorimetry. The enthalpy of formation from the oxides were calculated from the enthalpies of drop solution to be -87.1±9.6, -94.9±8.8, and -93.1±8.7 kJ/mol for LaTa-OH, LaTa-850, and LaTa-1200, respectively. These results indicate that the intermediate phase, LaTa-850, is the most stable. This pattern of energetics may be related to cationcation repulsion of the tantalate cations. We also investigated possible LnTaO4 and Ln2Ta2O7(OH)2 analogues of Ln=Pr, Nd to examine the relationship between cation size and the resulting phases.
Original language | English (US) |
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Pages (from-to) | 2516-2521 |
Number of pages | 6 |
Journal | Journal of Solid State Chemistry |
Volume | 183 |
Issue number | 11 |
DOIs | |
State | Published - Nov 2010 |
Externally published | Yes |
Keywords
- Calorimetry
- Lanthanum
- Rare earth
- Tantalate
ASJC Scopus subject areas
- Electronic, Optical and Magnetic Materials
- Ceramics and Composites
- Condensed Matter Physics
- Physical and Theoretical Chemistry
- Inorganic Chemistry
- Materials Chemistry