Synthesis and First Molecular Structure of a Bis-2-spiro-1-boraadamantane Derivative

Carl E. Wagner; Kenneth J. Shea

doi:10.1021/ol035661q

Synthesis and First Molecular Structure of a Bis-2-spiro-1-boraadamantane Derivative

Carl E. Wagner, Kenneth J. Shea

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

(Matrix presented) A new method for synthesizing the 2-spiro- boraadamantane pyridine complex (2) from 1-ethynylcyclohexylmethyl ether has been developed. The chemistry has been applied to the synthesis of bis-2-spiro-1-boraadamantane-pyridine (1) from trans-1,4-diethynyl-1,4- dimethoxycyclohexane (8). This bis-Lewis acid serves as a self-assembling molecular building block with difunctional Lewis bases.

Original language	English (US)
Pages (from-to)	313-316
Number of pages	4
Journal	Organic Letters
Volume	6
Issue number	3
DOIs	https://doi.org/10.1021/ol035661q
State	Published - Feb 5 2004
Externally published	Yes

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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abstract = "(Matrix presented) A new method for synthesizing the 2-spiro- boraadamantane pyridine complex (2) from 1-ethynylcyclohexylmethyl ether has been developed. The chemistry has been applied to the synthesis of bis-2-spiro-1-boraadamantane-pyridine (1) from trans-1,4-diethynyl-1,4- dimethoxycyclohexane (8). This bis-Lewis acid serves as a self-assembling molecular building block with difunctional Lewis bases.",

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doi = "10.1021/ol035661q",

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AU - Shea, Kenneth J.

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N2 - (Matrix presented) A new method for synthesizing the 2-spiro- boraadamantane pyridine complex (2) from 1-ethynylcyclohexylmethyl ether has been developed. The chemistry has been applied to the synthesis of bis-2-spiro-1-boraadamantane-pyridine (1) from trans-1,4-diethynyl-1,4- dimethoxycyclohexane (8). This bis-Lewis acid serves as a self-assembling molecular building block with difunctional Lewis bases.

AB - (Matrix presented) A new method for synthesizing the 2-spiro- boraadamantane pyridine complex (2) from 1-ethynylcyclohexylmethyl ether has been developed. The chemistry has been applied to the synthesis of bis-2-spiro-1-boraadamantane-pyridine (1) from trans-1,4-diethynyl-1,4- dimethoxycyclohexane (8). This bis-Lewis acid serves as a self-assembling molecular building block with difunctional Lewis bases.

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Synthesis and First Molecular Structure of a Bis-2-spiro-1-boraadamantane Derivative

Abstract

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