Synthesis and First Molecular Structure of a Bis-2-spiro-1-boraadamantane Derivative

Carl E. Wagner, Kenneth J. Shea

Research output: Contribution to journalArticlepeer-review

7 Scopus citations

Abstract

(Matrix presented) A new method for synthesizing the 2-spiro- boraadamantane pyridine complex (2) from 1-ethynylcyclohexylmethyl ether has been developed. The chemistry has been applied to the synthesis of bis-2-spiro-1-boraadamantane-pyridine (1) from trans-1,4-diethynyl-1,4- dimethoxycyclohexane (8). This bis-Lewis acid serves as a self-assembling molecular building block with difunctional Lewis bases.

Original languageEnglish (US)
Pages (from-to)313-316
Number of pages4
JournalOrganic Letters
Volume6
Issue number3
DOIs
StatePublished - Feb 5 2004
Externally publishedYes

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

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