TY - JOUR
T1 - Super-Stable High-Quality Few-Layer Black Phosphorus for Photonic Applications
AU - Li, Dongying
AU - Yu, Yueyang
AU - Ning, Cun Zheng
N1 - Funding Information:
The authors thank Kenneth Mossman and Manuel A. Roldan Gutierrez for STEM characterization. We gratefully acknowledge the use of facilities at the NanoFab and Eyring Materials Center at Arizona State University. This work was supported by the NSF under Grant ECCS-1807644.
Publisher Copyright:
© 2021 American Chemical Society.
PY - 2021/5/28
Y1 - 2021/5/28
N2 - Few-layer black phosphorus (BP) is one of the most important 2D materials due to its strongly layer-dependent quantized band structure, which leads to wavelength tunable emission and absorption properties. Such properties are essential for a variety of photonic device applications such as lasers, detectors, and modulators in a wide range of near-infrared wavelengths. However, the material quality and stability have become a bottleneck along with other challenges such as poor light emission properties and considerable uncertainty of basic material parameters. In this paper, we developed a systematic strategy for preparing high-quality stable few-layer BP samples by combining O2 plasma etching, boron nitride sandwiching, and subsequent thermal annealing. Our strategy has successfully produced few-layer BP samples with a record-long lifetime, with 80% of photoluminescence intensity remaining after 7 months. Importantly, we found that lattice reconstruction and reparation of oxidized BP surfaces increased BP thickness by one monolayer, leading to the restoration of BP crystal structure, improved material quality and stability, and restoration of intrinsic optical properties. As a result, 200× PL enhancement and 2× line width reduction are achieved, allowing the establishment of a more definite relationship between the layer number and PL energies for the first time. Our results could help unleash the full potential of few-layer BP in photonics applications in a wide range of near-infrared wavelengths.
AB - Few-layer black phosphorus (BP) is one of the most important 2D materials due to its strongly layer-dependent quantized band structure, which leads to wavelength tunable emission and absorption properties. Such properties are essential for a variety of photonic device applications such as lasers, detectors, and modulators in a wide range of near-infrared wavelengths. However, the material quality and stability have become a bottleneck along with other challenges such as poor light emission properties and considerable uncertainty of basic material parameters. In this paper, we developed a systematic strategy for preparing high-quality stable few-layer BP samples by combining O2 plasma etching, boron nitride sandwiching, and subsequent thermal annealing. Our strategy has successfully produced few-layer BP samples with a record-long lifetime, with 80% of photoluminescence intensity remaining after 7 months. Importantly, we found that lattice reconstruction and reparation of oxidized BP surfaces increased BP thickness by one monolayer, leading to the restoration of BP crystal structure, improved material quality and stability, and restoration of intrinsic optical properties. As a result, 200× PL enhancement and 2× line width reduction are achieved, allowing the establishment of a more definite relationship between the layer number and PL energies for the first time. Our results could help unleash the full potential of few-layer BP in photonics applications in a wide range of near-infrared wavelengths.
KW - annealing
KW - few-layer black phosphorus
KW - lattice reconstruction
KW - photoluminescence
KW - stability
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U2 - 10.1021/acsanm.1c00351
DO - 10.1021/acsanm.1c00351
M3 - Article
AN - SCOPUS:85106645935
SN - 2574-0970
VL - 4
SP - 4746
EP - 4753
JO - ACS Applied Nano Materials
JF - ACS Applied Nano Materials
IS - 5
ER -