Abstract
A new brittle hydrocarbon has been successfully synthesized in polycrystalline form, and its crystal structure solved by quantitative electron diffraction. By 3D tilting of the nano-crystals, the lattice type and unit cell parameters were determined. (Triclinic, a=6.03Å, b=6.23Å, c=13.86Å, α=87.26°, β=106.69°, and γ=119.01°. ) Spot diffraction patterns were obtained at -165°C using the Koehler selected-area mode on a LEO 912 TEM fitted with an omega in-column elastic energy filter. The direct methods algorithm was then applied to merged intensities and a trial structure obtained assuming single scattering. This was further refined to obtain good agreement with a small residual of about 10% using multiple scattering calculations. A diagram of the proposed structure is given.
Original language | English (US) |
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Pages (from-to) | 145-150 |
Number of pages | 6 |
Journal | Ultramicroscopy |
Volume | 98 |
Issue number | 2-4 |
DOIs | |
State | Published - Jan 2004 |
Keywords
- 006
- 011
- 61.14.Dc
- 61.14.Lj
- 61.66.Hq
- Electron crystallography
- Electron diffraction
- Electron microscopy
- Molecular structure
- Structure of organic crystal
ASJC Scopus subject areas
- Electronic, Optical and Magnetic Materials
- Atomic and Molecular Physics, and Optics
- Instrumentation