Abstract
Œstrone has been converted into 14α-methylœstr-4-ene-3, 15-dione (V) in 14 steps. Direct alkylation at position 14 (activated by a 15-oxo-group) proved convenient for introducing the angular methyl group. Configuration of the 14-methyl substituent was established by o.r.d. measurements.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 2024-2026 |
| Number of pages | 3 |
| Journal | Journal of the Chemical Society C: Organic Chemistry |
| DOIs | |
| State | Published - 1967 |
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ASJC Scopus subject areas
- Organic Chemistry
Cite this
Steroids and related natural products. Part XLI. 14α-Methyl Œstranes. / Pettit, George; Brown, Thomas H.
In: Journal of the Chemical Society C: Organic Chemistry, 1967, p. 2024-2026.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Steroids and related natural products. Part XLI. 14α-Methyl Œstranes
AU - Pettit, George
AU - Brown, Thomas H.
PY - 1967
Y1 - 1967
N2 - Œstrone has been converted into 14α-methylœstr-4-ene-3, 15-dione (V) in 14 steps. Direct alkylation at position 14 (activated by a 15-oxo-group) proved convenient for introducing the angular methyl group. Configuration of the 14-methyl substituent was established by o.r.d. measurements.
AB - Œstrone has been converted into 14α-methylœstr-4-ene-3, 15-dione (V) in 14 steps. Direct alkylation at position 14 (activated by a 15-oxo-group) proved convenient for introducing the angular methyl group. Configuration of the 14-methyl substituent was established by o.r.d. measurements.
UR - http://www.scopus.com/inward/record.url?scp=37049116461&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=37049116461&partnerID=8YFLogxK
U2 - 10.1039/J39670002024
DO - 10.1039/J39670002024
M3 - Article
AN - SCOPUS:37049116461
SP - 2024
EP - 2026
JO - Journal of the Chemical Society C: Organic Chemistry
JF - Journal of the Chemical Society C: Organic Chemistry
SN - 0022-4952
ER -