TY - JOUR
T1 - Spinel-structured gallium oxynitride (Ga 3O 3N) synthesis and characterization
T2 - An experimental and theoretical study
AU - Soignard, Emmanuel
AU - Machon, Denis
AU - McMillan, Paul F.
AU - Dong, Jianjun
AU - Xu, Bin
AU - Leinenweber, Kurt
PY - 2005/11/1
Y1 - 2005/11/1
N2 - Recently the new family of spinel-structured nitrides and oxynitrides of group 14 elements (Si, Ge, Sn) has been explored using high-pressure synthesis techniques. The solid-state compounds have high hardness, and they are semiconducting materials that are predicted to have a wide direct band gap. Here we have prepared the corresponding gallium oxynitride spinel with ideal formula G 3O 3N. The synthesis conditions and stability of the new phase were predicted using first-principles calculations, and the experimental study was realized using a combination of laser-heated diamond anvil cell and multianvil high-pressure, high-temperature synthesis techniques. Chemical analysis and X-ray structure refinement indicate that the new phase contains vacancies on the octahedrally coordinated Ga sites, to give an experimental stoichiometry of Ga 2.8N 0.64O 3.24. The Raman spectrum consists of broad bands and resembles the phonon density of states, due to N/O disorder on the anion sites. Optical excitation of the sample with 325 nm laser light at room temperature results in strong photoluminescence between 400 and 750 nm.
AB - Recently the new family of spinel-structured nitrides and oxynitrides of group 14 elements (Si, Ge, Sn) has been explored using high-pressure synthesis techniques. The solid-state compounds have high hardness, and they are semiconducting materials that are predicted to have a wide direct band gap. Here we have prepared the corresponding gallium oxynitride spinel with ideal formula G 3O 3N. The synthesis conditions and stability of the new phase were predicted using first-principles calculations, and the experimental study was realized using a combination of laser-heated diamond anvil cell and multianvil high-pressure, high-temperature synthesis techniques. Chemical analysis and X-ray structure refinement indicate that the new phase contains vacancies on the octahedrally coordinated Ga sites, to give an experimental stoichiometry of Ga 2.8N 0.64O 3.24. The Raman spectrum consists of broad bands and resembles the phonon density of states, due to N/O disorder on the anion sites. Optical excitation of the sample with 325 nm laser light at room temperature results in strong photoluminescence between 400 and 750 nm.
UR - http://www.scopus.com/inward/record.url?scp=27744568427&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=27744568427&partnerID=8YFLogxK
U2 - 10.1021/cm051224p
DO - 10.1021/cm051224p
M3 - Article
AN - SCOPUS:27744568427
SN - 0897-4756
VL - 17
SP - 5465
EP - 5472
JO - Chemistry of Materials
JF - Chemistry of Materials
IS - 22
ER -