Spectroscopy of N2+ Meinel bands and CO+ comet tail bands

C. H. Kuo, I. W. Milkman, Timothy Steimle, J. T. Moseley

Research output: Contribution to journalArticle

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Abstract

The N2+ [X2 Σg +(v″=0)-A 2Πu(v′=5)] Meinel band and the CO+[X 2Σ+(v″=0)-A 2Π(v′=1,2)] comet tail bands have been measured with Doppler-limited resolution in a selected ion flow tube (SIFT) apparatus using laser induced charge transfer. The charge transfer medium was Ar, which does not react with those ions in their ground levels, but undergoes a strong charge transfer reaction with the excited states under consideration here. The use of a single mode laser and the SIFT technique led to much higher signal-to-noise than obtained in earlier work. These measurements are the first reported with Doppler-limited resolution on any of these bands, and are analyzed to provide substantially improved molecular constants for the excited states involved in the transitions.

Original languageEnglish (US)
Pages (from-to)4269-4275
Number of pages7
JournalThe Journal of chemical physics
Volume85
Issue number8
DOIs
StatePublished - Jan 1 1986

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ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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