Size-resolved organic speciation of wintertime aerosols in california's central valley

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

Size-resolved aerosol samples, including the entire ultrafine fraction, were simultaneously collected along a transect in California's Central Valley during the winter of 2009. The samples were analyzed for PAHs, alkanes, organic acids, and sugars. The results showed that the organic constituents of aerosols did not follow the same pattern as PM10, thus indicating that simple PM measurements are not good indicators of trace toxic organic chemicals. Levoglucosan, a tracer of wood smoke, was the most abundant organic chemical detected, thus demonstrating the predominance of wood smoke in the valley. The size profile of levoglucosan showed a maximum in the 0.34-0.56 μm size mode, which is larger than published emission profiles. This suggests that wood smoke aerosols increased in size as they aged in the environment Some chemicals, such as benzo[a]pyrene, had similar aerosol size profiles as levoglucosan and likely arose from the same source. Other chemicals, such as coronene and sugars, had very different size profiles, indicating that they have different sources. One unexpected result was the relatively large fraction of certain chemicals present in the ultrafine fraction, which highlights the importance of collecting the entire ultrafine fraction.

Original languageEnglish (US)
Pages (from-to)2315-2321
Number of pages7
JournalEnvironmental Science and Technology
Volume44
Issue number7
DOIs
StatePublished - Apr 1 2010

Fingerprint

Aerosols
Smoke
smoke
aerosol
Organic Chemicals
valley
Wood
sugar
particle size
Sugar Acids
Alkanes
Poisons
Benzo(a)pyrene
Organic acids
Polycyclic aromatic hydrocarbons
organic acid
pyrene
Sugars
alkane
PAH

ASJC Scopus subject areas

  • Chemistry(all)
  • Environmental Chemistry

Cite this

Size-resolved organic speciation of wintertime aerosols in california's central valley. / Cahill, Thomas.

In: Environmental Science and Technology, Vol. 44, No. 7, 01.04.2010, p. 2315-2321.

Research output: Contribution to journalArticle

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