Regularities in charge transfer through metal-electrolyte boundaries under the influence of thermal fluctuations of the solvent

Z. V. Gorodyskii; A. I. Karasevskii; Dmitry Matyushov; E. V. Panov

Regularities in charge transfer through metal-electrolyte boundaries under the influence of thermal fluctuations of the solvent

Z. V. Gorodyskii, A. I. Karasevskii, Dmitry Matyushov, E. V. Panov

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Abstract

Electron transfer from an ion to the cathode is theoretically examined in adiabatic electrode reactions. Two independent conditions are possible for the occurrence of the reactions, viz., due to the desolvation of an ion on the electrode surface or due to thermal fluctuations of the melt near the ion. Equations are derived for the polarization curve under both conditions.

Original language	English (US)
Title of host publication	Melts
Pages	407-412
Number of pages	6
Volume	2
Edition	5
State	Published - Jan 1990
Externally published	Yes

ASJC Scopus subject areas

Engineering(all)

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title = "Regularities in charge transfer through metal-electrolyte boundaries under the influence of thermal fluctuations of the solvent",

abstract = "Electron transfer from an ion to the cathode is theoretically examined in adiabatic electrode reactions. Two independent conditions are possible for the occurrence of the reactions, viz., due to the desolvation of an ion on the electrode surface or due to thermal fluctuations of the melt near the ion. Equations are derived for the polarization curve under both conditions.",

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AU - Gorodyskii, Z. V.

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AU - Matyushov, Dmitry

AU - Panov, E. V.

PY - 1990/1

Y1 - 1990/1

N2 - Electron transfer from an ion to the cathode is theoretically examined in adiabatic electrode reactions. Two independent conditions are possible for the occurrence of the reactions, viz., due to the desolvation of an ion on the electrode surface or due to thermal fluctuations of the melt near the ion. Equations are derived for the polarization curve under both conditions.

AB - Electron transfer from an ion to the cathode is theoretically examined in adiabatic electrode reactions. Two independent conditions are possible for the occurrence of the reactions, viz., due to the desolvation of an ion on the electrode surface or due to thermal fluctuations of the melt near the ion. Equations are derived for the polarization curve under both conditions.

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VL - 2

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BT - Melts

ER -

Regularities in charge transfer through metal-electrolyte boundaries under the influence of thermal fluctuations of the solvent

Abstract

ASJC Scopus subject areas

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