Regularities in charge transfer through metal-electrolyte boundaries under the influence of thermal fluctuations of the solvent

Z. V. Gorodyskii, A. I. Karasevskii, Dmitry Matyushov, E. V. Panov

Research output: Chapter in Book/Report/Conference proceedingChapter

Abstract

Electron transfer from an ion to the cathode is theoretically examined in adiabatic electrode reactions. Two independent conditions are possible for the occurrence of the reactions, viz., due to the desolvation of an ion on the electrode surface or due to thermal fluctuations of the melt near the ion. Equations are derived for the polarization curve under both conditions.

Original languageEnglish (US)
Title of host publicationMelts
Pages407-412
Number of pages6
Volume2
Edition5
StatePublished - Jan 1990
Externally publishedYes

ASJC Scopus subject areas

  • Engineering(all)

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