TY - GEN
T1 - Preparation of nanoporous MgAl 2O 4 by combined utilization of sol-gel process and combustion of biorenewable oil
AU - Hörtz, Christian
AU - Ladd, Danielle M.
AU - Seo, Dong
PY - 2011
Y1 - 2011
N2 - Nanoporous MgAl 2O 4 particulates with high porosities were successfully prepared from sol-gel reactions, solvent exchange with castor oil and subsequent combustion and calcination at 700 °C. The products were crystalline and semitransparent. Changes in the metal precursor concentrations allowed control of pore volumes from 0.7 to 1.1 cm 3/g and average pore sizes from 14 to 19 nm. The specific surface areas are about 200 m 2/g regardless of the precursor concentrations. After heating at 1000 °C for 10 hours, the products kept about 70% of their original pore volume and about 60% of the original surface area. Heating at 1100 °C caused a drastic reduction of pore volume and surface area to 40 and 36%, respectively, as the average particle size increased to 23 nm.
AB - Nanoporous MgAl 2O 4 particulates with high porosities were successfully prepared from sol-gel reactions, solvent exchange with castor oil and subsequent combustion and calcination at 700 °C. The products were crystalline and semitransparent. Changes in the metal precursor concentrations allowed control of pore volumes from 0.7 to 1.1 cm 3/g and average pore sizes from 14 to 19 nm. The specific surface areas are about 200 m 2/g regardless of the precursor concentrations. After heating at 1000 °C for 10 hours, the products kept about 70% of their original pore volume and about 60% of the original surface area. Heating at 1100 °C caused a drastic reduction of pore volume and surface area to 40 and 36%, respectively, as the average particle size increased to 23 nm.
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U2 - 10.1557/opl.2011.418
DO - 10.1557/opl.2011.418
M3 - Conference contribution
AN - SCOPUS:84860146523
SN - 9781618395139
T3 - Materials Research Society Symposium Proceedings
SP - 98
EP - 103
BT - Aerogels and Aerogel-Inspired Materials
T2 - 2010 MRS Fall Meeting
Y2 - 29 November 2010 through 3 December 2010
ER -