Novel Surface Molecular Functionalization Route to Enhance Environmental Stability of Tellurium Containing 2D Layers

Sijie Yang, Ying Qin, Bin Chen, V. Ongun Özçelik, Claire E. White, Yuxia Shen, Shengxue Yang, Sefaattin Tongay

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

Recent studies have shown that tellurium based 2D crystals undergo dramatic structural, physical, and chemical changes under ambient conditions. This not only adversely impacts their much desired properties, but also is a roadblock for their applications. Here, we introduce diazonium molecule functionalization based surface engineering route that greatly enhances their environmental stability without sacrificing their much desired properties. Spectroscopy and microscopy results show that diazonium groups significantly slow down the surface reactions, and consequently gallium telluride (GaTe), zirconium telluride (ZrTe3) and molybdenum ditelluride (MoTe2) gain strong resistance to surface transformation in air or when immersed under water. Density functional theory calculations show functionalizing molecules reduces surface reactivity of Te-containing 2D surfaces by chemical binding followed by electron withdrawal process. While pristine surfaces structurally decompose due to strong reactivity of Te surface atoms, passivated functionalized surfaces retain their structural anisotropy, optical band gap, and emission characteristics as evidenced by our conductive AFM, PL and absorption spectroscopy measurements. Overall, our findings offer an effective method to increase the stability of these environmentally sensitive materials without impacting much of their physical properties.

Original languageEnglish (US)
JournalUnknown Journal
DOIs
StateAccepted/In press - Feb 10 2017

Fingerprint

Tellurium
Spectrum Analysis
Gallium
Anisotropy
Microscopy
Air
Electrons
Water
Molecules
Optical band gaps
Surface reactions
Absorption spectroscopy
Zirconium
Molybdenum
Density functional theory
Microscopic examination
Physical properties
Spectroscopy
Atoms
Crystals

Keywords

  • 2D materials
  • chemical functionalization
  • degradation
  • environmental stability
  • spectroscopy

ASJC Scopus subject areas

  • Materials Science(all)

Cite this

Novel Surface Molecular Functionalization Route to Enhance Environmental Stability of Tellurium Containing 2D Layers. / Yang, Sijie; Qin, Ying; Chen, Bin; Özçelik, V. Ongun; White, Claire E.; Shen, Yuxia; Yang, Shengxue; Tongay, Sefaattin.

In: Unknown Journal, 10.02.2017.

Research output: Contribution to journalArticle

Yang, Sijie ; Qin, Ying ; Chen, Bin ; Özçelik, V. Ongun ; White, Claire E. ; Shen, Yuxia ; Yang, Shengxue ; Tongay, Sefaattin. / Novel Surface Molecular Functionalization Route to Enhance Environmental Stability of Tellurium Containing 2D Layers. In: Unknown Journal. 2017.
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