NOVEL ELECTROLYTE SYSTEM

SOLUTIONS OF DIETHYL ETHER IN CONCENTRATED AQUEOUS HCl plus ZnCl//2 MIXTURES.

A. J. Easteal, Charles Angell

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

The solubility in this mixture increases with decreasing temperature, down to the glass transition temperature at minus 124 C. Although ionic mobilities appear to increase with increasing ether content the electrical conductance at 0 C decreases, evidently due to the disruption of an efficient proton transfer mechanism in the chlorozincate acid. The strongly proton conducting solutions may have useful low temperature electrolyte applications, since the conductivity is not necessarily limited by the ionic and molecular transport mechanisms which determine the fluidity.

Original languageEnglish (US)
Pages (from-to)1143-1145
Number of pages3
JournalJournal of the Electrochemical Society
Volume120
Issue number9
StatePublished - Sep 1973
Externally publishedYes

Fingerprint

diethyl ether
Ether
Electrolytes
Ethers
electrolytes
ionic mobility
Proton transfer
protons
Fluidity
glass transition temperature
Protons
ethers
solubility
Solubility
conduction
conductivity
Temperature
acids
Acids
temperature

ASJC Scopus subject areas

  • Electrochemistry
  • Surfaces, Coatings and Films
  • Surfaces and Interfaces

Cite this

NOVEL ELECTROLYTE SYSTEM : SOLUTIONS OF DIETHYL ETHER IN CONCENTRATED AQUEOUS HCl plus ZnCl//2 MIXTURES. / Easteal, A. J.; Angell, Charles.

In: Journal of the Electrochemical Society, Vol. 120, No. 9, 09.1973, p. 1143-1145.

Research output: Contribution to journalArticle

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