Non-conventional synthesis and magnetic properties of MAX phases (Cr/Mn)2AlC and (Cr/Fe)2AlC

Christin M. Hamm, Joshua D. Bocarsly, Gareth Seward, Ulrike I. Kramm, Christina S. Birkel

Research output: Contribution to journalArticle

13 Citations (Scopus)

Abstract

A few years after the theoretical prediction of magnetic MAX phases, a number of such materials have been experimentally reported, especially in the form of thin films. Yet, due to a relatively small number of studies, we have only just begun to discover the intriguing magnetic properties that are associated with this class of materials. The preparation of bulk MAX phases with later transition metals has been proven to be particularly challenging. Consequentially, there is a great need to develop synthetic strategies to obtain the respective materials in suitable quantities for magnetic investigations. Here, bulk Mn-and Fe-substituted Cr2AlC are prepared using non-conventional synthesis methods such as microwave heating and spark plasma sintering. Synchrotron X-ray diffraction coupled with detailed elemental analyses is used to confirm the successful doping of the MAX phase with the later transition metals as well as to elucidate the microstructure of the obtained dense materials. 7Fe Mössbauer spectroscopy data are presented showing signals of the doped MAX phase and Fe-containing secondary phases. Based on PPMS and SQUID measurements the non-Trivial magnetic behavior of the obtained samples is discussed in the context of the existing studies.

Original languageEnglish (US)
Pages (from-to)5700-5708
Number of pages9
JournalJournal of Materials Chemistry C
Volume5
Issue number23
DOIs
StatePublished - Jan 1 2017
Externally publishedYes

Fingerprint

Magnetic properties
Transition metals
Microwave heating
Spark plasma sintering
SQUIDs
Synchrotrons
Doping (additives)
Spectroscopy
X ray diffraction
Thin films
Microstructure

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Chemistry

Cite this

Non-conventional synthesis and magnetic properties of MAX phases (Cr/Mn)2AlC and (Cr/Fe)2AlC. / Hamm, Christin M.; Bocarsly, Joshua D.; Seward, Gareth; Kramm, Ulrike I.; Birkel, Christina S.

In: Journal of Materials Chemistry C, Vol. 5, No. 23, 01.01.2017, p. 5700-5708.

Research output: Contribution to journalArticle

Hamm, Christin M. ; Bocarsly, Joshua D. ; Seward, Gareth ; Kramm, Ulrike I. ; Birkel, Christina S. / Non-conventional synthesis and magnetic properties of MAX phases (Cr/Mn)2AlC and (Cr/Fe)2AlC. In: Journal of Materials Chemistry C. 2017 ; Vol. 5, No. 23. pp. 5700-5708.
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