Morphology of NiSi film on Si(100): role of the interface strain

Eliane Maillard-Schaller, B. I. Boyanov, S. English, Robert Nemanich

Research output: Chapter in Book/Report/Conference proceedingConference contribution

1 Citation (Scopus)

Abstract

The role of strain on the thermal stability of NiSi has been studied by deposition and annealing of Ni on strained and relaxed Si(100) n-type substrates. Strained Si substrates have been produced by depositing a pseudomorphic silicon film on top of a 3000 angstrom thick relaxed Si 0.8Ge 0.2 film. Raman spectroscopy has proved the top silicon film to be strained. The presence of the characteristic hatch-cross pattern has been confirmed by Atomic Force Microscopy (AFM). Scanning electron microscopy (SEM) and Photoelectron emission microscopy (PEEM) show that the islanding of the NiSi film appears at lower temperature on the bulk silicon substrate (600°C) than on the strained silicon substrate (700°C). The improved thermal stability of NiSi on strained Si can be explained by the difference in relative interface energy of NiSi on strained and relaxed silicon. The thermal expansion coefficient of Ni being 3 times larger than that of Si, NiSi is in compression on Si at 500°C already. The correlation of this compression state with the lattice parameters of bulk and strained Si (100) produces an increased NiSi islanding probability on bulk Si (100) with respect to strained Si.

Original languageEnglish (US)
Title of host publicationMaterials Research Society Symposium - Proceedings
PublisherMRS
Pages185-189
Number of pages5
Volume514
StatePublished - 1998
Externally publishedYes
EventProceedings of the 1998 MRS Spring Symposium - San Francisco, CA, USA
Duration: Apr 13 1998Apr 16 1998

Other

OtherProceedings of the 1998 MRS Spring Symposium
CitySan Francisco, CA, USA
Period4/13/984/16/98

Fingerprint

Silicon
Substrates
Thermodynamic stability
Hatches
Photoelectrons
Lattice constants
Thermal expansion
Raman spectroscopy
Atomic force microscopy
Microscopic examination
Annealing
Scanning electron microscopy
Temperature

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials

Cite this

Maillard-Schaller, E., Boyanov, B. I., English, S., & Nemanich, R. (1998). Morphology of NiSi film on Si(100): role of the interface strain. In Materials Research Society Symposium - Proceedings (Vol. 514, pp. 185-189). MRS.

Morphology of NiSi film on Si(100) : role of the interface strain. / Maillard-Schaller, Eliane; Boyanov, B. I.; English, S.; Nemanich, Robert.

Materials Research Society Symposium - Proceedings. Vol. 514 MRS, 1998. p. 185-189.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Maillard-Schaller, E, Boyanov, BI, English, S & Nemanich, R 1998, Morphology of NiSi film on Si(100): role of the interface strain. in Materials Research Society Symposium - Proceedings. vol. 514, MRS, pp. 185-189, Proceedings of the 1998 MRS Spring Symposium, San Francisco, CA, USA, 4/13/98.
Maillard-Schaller E, Boyanov BI, English S, Nemanich R. Morphology of NiSi film on Si(100): role of the interface strain. In Materials Research Society Symposium - Proceedings. Vol. 514. MRS. 1998. p. 185-189
Maillard-Schaller, Eliane ; Boyanov, B. I. ; English, S. ; Nemanich, Robert. / Morphology of NiSi film on Si(100) : role of the interface strain. Materials Research Society Symposium - Proceedings. Vol. 514 MRS, 1998. pp. 185-189
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N2 - The role of strain on the thermal stability of NiSi has been studied by deposition and annealing of Ni on strained and relaxed Si(100) n-type substrates. Strained Si substrates have been produced by depositing a pseudomorphic silicon film on top of a 3000 angstrom thick relaxed Si 0.8Ge 0.2 film. Raman spectroscopy has proved the top silicon film to be strained. The presence of the characteristic hatch-cross pattern has been confirmed by Atomic Force Microscopy (AFM). Scanning electron microscopy (SEM) and Photoelectron emission microscopy (PEEM) show that the islanding of the NiSi film appears at lower temperature on the bulk silicon substrate (600°C) than on the strained silicon substrate (700°C). The improved thermal stability of NiSi on strained Si can be explained by the difference in relative interface energy of NiSi on strained and relaxed silicon. The thermal expansion coefficient of Ni being 3 times larger than that of Si, NiSi is in compression on Si at 500°C already. The correlation of this compression state with the lattice parameters of bulk and strained Si (100) produces an increased NiSi islanding probability on bulk Si (100) with respect to strained Si.

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