More active Ir subnanometer clusters than single-atoms for catalytic oxidation of CO at low temperature

Jian Lin, Yang Chen, Yanliang Zhou, Lin Li, Botao Qiao, Aiqin Wang, Jingyue Liu, Xiaodong Wang, Tao Zhang

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

This work reported the adsorption and reaction performance of FeOx supported subnanometer cluster and single-atom Ir catalysts for the oxidation of CO at low temperature. By varying the pretreatment temperature and Ir loading, the single-atom and subnanometer cluster Ir catalysts were obtained. The Ir subnanometer clusters exhibited higher activity for the oxidation of CO with or without the presence of H2 than the single-atom counterpart. By using adsorption microcalorimetry and in situ infrared spectroscopy measurements, it was found that the Ir subnanometer clusters not only promoted the adsorption and reaction of CO and O2 but also facilitated the formation of OH species from reaction between H2 and O2, thus opening a new reaction pathway between CO and OH species to produce CO2 compared with that between CO and O species on the single-atom counterpart.

Original languageEnglish (US)
JournalAICHE Journal
DOIs
StateAccepted/In press - 2017

Fingerprint

Catalytic oxidation
Carbon Monoxide
Atoms
Temperature
Adsorption
Oxidation
Catalysts
Infrared spectroscopy
Spectrum Analysis

Keywords

  • CO oxidation
  • CO
  • Ir
  • Single atoms
  • Subnanometer clusters

ASJC Scopus subject areas

  • Biotechnology
  • Environmental Engineering
  • Chemical Engineering(all)

Cite this

More active Ir subnanometer clusters than single-atoms for catalytic oxidation of CO at low temperature. / Lin, Jian; Chen, Yang; Zhou, Yanliang; Li, Lin; Qiao, Botao; Wang, Aiqin; Liu, Jingyue; Wang, Xiaodong; Zhang, Tao.

In: AICHE Journal, 2017.

Research output: Contribution to journalArticle

Lin, Jian ; Chen, Yang ; Zhou, Yanliang ; Li, Lin ; Qiao, Botao ; Wang, Aiqin ; Liu, Jingyue ; Wang, Xiaodong ; Zhang, Tao. / More active Ir subnanometer clusters than single-atoms for catalytic oxidation of CO at low temperature. In: AICHE Journal. 2017.
@article{61eeea7475bc45dc8fb46a557fe13c22,
title = "More active Ir subnanometer clusters than single-atoms for catalytic oxidation of CO at low temperature",
abstract = "This work reported the adsorption and reaction performance of FeOx supported subnanometer cluster and single-atom Ir catalysts for the oxidation of CO at low temperature. By varying the pretreatment temperature and Ir loading, the single-atom and subnanometer cluster Ir catalysts were obtained. The Ir subnanometer clusters exhibited higher activity for the oxidation of CO with or without the presence of H2 than the single-atom counterpart. By using adsorption microcalorimetry and in situ infrared spectroscopy measurements, it was found that the Ir subnanometer clusters not only promoted the adsorption and reaction of CO and O2 but also facilitated the formation of OH species from reaction between H2 and O2, thus opening a new reaction pathway between CO and OH species to produce CO2 compared with that between CO and O species on the single-atom counterpart.",
keywords = "CO oxidation, CO, Ir, Single atoms, Subnanometer clusters",
author = "Jian Lin and Yang Chen and Yanliang Zhou and Lin Li and Botao Qiao and Aiqin Wang and Jingyue Liu and Xiaodong Wang and Tao Zhang",
year = "2017",
doi = "10.1002/aic.15756",
language = "English (US)",
journal = "AICHE Journal",
issn = "0001-1541",
publisher = "American Institute of Chemical Engineers",

}

TY - JOUR

T1 - More active Ir subnanometer clusters than single-atoms for catalytic oxidation of CO at low temperature

AU - Lin, Jian

AU - Chen, Yang

AU - Zhou, Yanliang

AU - Li, Lin

AU - Qiao, Botao

AU - Wang, Aiqin

AU - Liu, Jingyue

AU - Wang, Xiaodong

AU - Zhang, Tao

PY - 2017

Y1 - 2017

N2 - This work reported the adsorption and reaction performance of FeOx supported subnanometer cluster and single-atom Ir catalysts for the oxidation of CO at low temperature. By varying the pretreatment temperature and Ir loading, the single-atom and subnanometer cluster Ir catalysts were obtained. The Ir subnanometer clusters exhibited higher activity for the oxidation of CO with or without the presence of H2 than the single-atom counterpart. By using adsorption microcalorimetry and in situ infrared spectroscopy measurements, it was found that the Ir subnanometer clusters not only promoted the adsorption and reaction of CO and O2 but also facilitated the formation of OH species from reaction between H2 and O2, thus opening a new reaction pathway between CO and OH species to produce CO2 compared with that between CO and O species on the single-atom counterpart.

AB - This work reported the adsorption and reaction performance of FeOx supported subnanometer cluster and single-atom Ir catalysts for the oxidation of CO at low temperature. By varying the pretreatment temperature and Ir loading, the single-atom and subnanometer cluster Ir catalysts were obtained. The Ir subnanometer clusters exhibited higher activity for the oxidation of CO with or without the presence of H2 than the single-atom counterpart. By using adsorption microcalorimetry and in situ infrared spectroscopy measurements, it was found that the Ir subnanometer clusters not only promoted the adsorption and reaction of CO and O2 but also facilitated the formation of OH species from reaction between H2 and O2, thus opening a new reaction pathway between CO and OH species to produce CO2 compared with that between CO and O species on the single-atom counterpart.

KW - CO oxidation

KW - CO

KW - Ir

KW - Single atoms

KW - Subnanometer clusters

UR - http://www.scopus.com/inward/record.url?scp=85018733315&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85018733315&partnerID=8YFLogxK

U2 - 10.1002/aic.15756

DO - 10.1002/aic.15756

M3 - Article

AN - SCOPUS:85018733315

JO - AICHE Journal

JF - AICHE Journal

SN - 0001-1541

ER -