Metallo-organic molecular sieve for gas separation and purification

Qing Min Wang; Dongmin Shen; Martin Bülow; Miu Ling Lau; Shuguang Deng; Frank R. Fitch; Norberto O. Lemcoff; Jessica Semanscin

doi:10.1016/S1387-1811(02)00405-5

Metallo-organic molecular sieve for gas separation and purification

Qing Min Wang, Dongmin Shen, Martin Bülow, Miu Ling Lau, Shuguang Deng, Frank R. Fitch, Norberto O. Lemcoff, Jessica Semanscin

Research output: Contribution to journal › Article › peer-review

722 Scopus citations

Abstract

An improved synthesis process was developed for large-scale production of a highly porous material, denoted as Cu-BTC, where BTC denotes benzene-1,3,5-tricarboxylate. A series of sorption properties for nitrogen, oxygen, carbon monoxide, carbon dioxide, nitrous oxide, methane, ethylene, ethane, n-dodecane, and water were studied. A detailed investigation of sorption thermodynamics was performed for carbon dioxide by a sorption-isosteric method. The experimental results show that Cu-BTC can be used for separation of gas mixtures such as carbon dioxide-carbon monoxide, carbon dioxide-methane and ethylene-ethane mixtures. In addition, air can be purified effectively from carbon dioxide, nitrous oxide, high-molecular weight hydrocarbons and moisture.

Original language	English (US)
Pages (from-to)	217-230
Number of pages	14
Journal	Microporous and Mesoporous Materials
Volume	55
Issue number	2
DOIs	https://doi.org/10.1016/S1387-1811(02)00405-5
State	Published - Sep 16 2002
Externally published	Yes

Keywords

Atmospheric gases
Gas mixtures
Hydrocarbons
Metallo-organic molecular-sieve synthesis
Polymeric copper(II) benzene-1,3,5-tricarboxylate
Sorption isosteres
Thermodynamic functions for CO

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics
Mechanics of Materials

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10.1016/S1387-1811(02)00405-5

Cite this

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title = "Metallo-organic molecular sieve for gas separation and purification",

abstract = "An improved synthesis process was developed for large-scale production of a highly porous material, denoted as Cu-BTC, where BTC denotes benzene-1,3,5-tricarboxylate. A series of sorption properties for nitrogen, oxygen, carbon monoxide, carbon dioxide, nitrous oxide, methane, ethylene, ethane, n-dodecane, and water were studied. A detailed investigation of sorption thermodynamics was performed for carbon dioxide by a sorption-isosteric method. The experimental results show that Cu-BTC can be used for separation of gas mixtures such as carbon dioxide-carbon monoxide, carbon dioxide-methane and ethylene-ethane mixtures. In addition, air can be purified effectively from carbon dioxide, nitrous oxide, high-molecular weight hydrocarbons and moisture.",

keywords = "Atmospheric gases, Gas mixtures, Hydrocarbons, Metallo-organic molecular-sieve synthesis, Polymeric copper(II) benzene-1,3,5-tricarboxylate, Sorption isosteres, Thermodynamic functions for CO",

author = "{Min Wang}, Qing and Dongmin Shen and Martin B{\"u}low and {Ling Lau}, Miu and Shuguang Deng and Fitch, {Frank R.} and Lemcoff, {Norberto O.} and Jessica Semanscin",

year = "2002",

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day = "16",

doi = "10.1016/S1387-1811(02)00405-5",

language = "English (US)",

volume = "55",

pages = "217--230",

journal = "Microporous and Mesoporous Materials",

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TY - JOUR

T1 - Metallo-organic molecular sieve for gas separation and purification

AU - Min Wang, Qing

AU - Shen, Dongmin

AU - Bülow, Martin

AU - Ling Lau, Miu

AU - Deng, Shuguang

AU - Fitch, Frank R.

AU - Lemcoff, Norberto O.

AU - Semanscin, Jessica

PY - 2002/9/16

Y1 - 2002/9/16

N2 - An improved synthesis process was developed for large-scale production of a highly porous material, denoted as Cu-BTC, where BTC denotes benzene-1,3,5-tricarboxylate. A series of sorption properties for nitrogen, oxygen, carbon monoxide, carbon dioxide, nitrous oxide, methane, ethylene, ethane, n-dodecane, and water were studied. A detailed investigation of sorption thermodynamics was performed for carbon dioxide by a sorption-isosteric method. The experimental results show that Cu-BTC can be used for separation of gas mixtures such as carbon dioxide-carbon monoxide, carbon dioxide-methane and ethylene-ethane mixtures. In addition, air can be purified effectively from carbon dioxide, nitrous oxide, high-molecular weight hydrocarbons and moisture.

AB - An improved synthesis process was developed for large-scale production of a highly porous material, denoted as Cu-BTC, where BTC denotes benzene-1,3,5-tricarboxylate. A series of sorption properties for nitrogen, oxygen, carbon monoxide, carbon dioxide, nitrous oxide, methane, ethylene, ethane, n-dodecane, and water were studied. A detailed investigation of sorption thermodynamics was performed for carbon dioxide by a sorption-isosteric method. The experimental results show that Cu-BTC can be used for separation of gas mixtures such as carbon dioxide-carbon monoxide, carbon dioxide-methane and ethylene-ethane mixtures. In addition, air can be purified effectively from carbon dioxide, nitrous oxide, high-molecular weight hydrocarbons and moisture.

KW - Atmospheric gases

KW - Gas mixtures

KW - Hydrocarbons

KW - Metallo-organic molecular-sieve synthesis

KW - Polymeric copper(II) benzene-1,3,5-tricarboxylate

KW - Sorption isosteres

KW - Thermodynamic functions for CO

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U2 - 10.1016/S1387-1811(02)00405-5

DO - 10.1016/S1387-1811(02)00405-5

M3 - Article

AN - SCOPUS:0037120243

SN - 1387-1811

VL - 55

SP - 217

EP - 230

JO - Microporous and Mesoporous Materials

JF - Microporous and Mesoporous Materials

IS - 2

ER -

Metallo-organic molecular sieve for gas separation and purification

Abstract

Keywords

ASJC Scopus subject areas

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