TY - JOUR
T1 - Mechanisms of pearlite spheroidization
T2 - Insights from 3D phase-field simulations
AU - Amos, P. G.Kubendran
AU - Bhattacharya, Avisor
AU - Nestler, Britta
AU - Ankit, Kumar
N1 - Funding Information:
AB and BN are thankful to the German Research Foundation for initiating the research topic and for funding the preliminary results within the cooperative framework of the Graduate School - 1483. PGKA, BN and KA acknowledge the financial support provided by German Research Foundation's Early-Career Investigator grant AN 1245/1-1 and College of Engineering, Arizona State University . The authors acknowledge fruitful discussions with Arnab Mukherjee, Ephraim Schoof and Daniel Schneider.
Publisher Copyright:
© 2018 Acta Materialia Inc.
PY - 2018/12
Y1 - 2018/12
N2 - Morphological evolution of eutectoid phases determine the spheroids’ size and distribution post sub-critical annealing of steel. In this work, the spheroidization of the 3-dimensional cementite plates is investigated via phase-field modeling to enhance our understanding of the underlying capillary-mediated mechanisms. Since the interfacial energy plays a key role in the spheroidization process, a phase-field model which efficiently avoids any contribution of the bulk free energy in the interface is employed to recover the sharp interface solutions. It is identified that depending on the cementite aspect ratio, the spheroidization mechanism adopted by the plate, varies. In plates of smaller aspect ratios (<27), the transformation is characterized by the recession of the edges and corners, following which, the entire plate collapses into a single spheroid. However, if the plate aspect ratios are greater than 27, discontinuities set-in due to a curvature-difference between the receding edges and the flat surfaces. Such discontinuities or holes continue to evolve and coalesce during the annealing process. Our phase-field simulation-based analysis of the cementite spheroidization provides the first exposure of the spatiotemporal pathways leading to the spheroidization of cementite. A change in the evolution mechanism from the ‘edge-migration regime ’ to a ‘discontinuities-assisted’ one, is found to be responsible for the fragmentation of cementite plates. The influence of the kinetic pathways on the resulting size and spatial distribution of the spheroids are discussed.
AB - Morphological evolution of eutectoid phases determine the spheroids’ size and distribution post sub-critical annealing of steel. In this work, the spheroidization of the 3-dimensional cementite plates is investigated via phase-field modeling to enhance our understanding of the underlying capillary-mediated mechanisms. Since the interfacial energy plays a key role in the spheroidization process, a phase-field model which efficiently avoids any contribution of the bulk free energy in the interface is employed to recover the sharp interface solutions. It is identified that depending on the cementite aspect ratio, the spheroidization mechanism adopted by the plate, varies. In plates of smaller aspect ratios (<27), the transformation is characterized by the recession of the edges and corners, following which, the entire plate collapses into a single spheroid. However, if the plate aspect ratios are greater than 27, discontinuities set-in due to a curvature-difference between the receding edges and the flat surfaces. Such discontinuities or holes continue to evolve and coalesce during the annealing process. Our phase-field simulation-based analysis of the cementite spheroidization provides the first exposure of the spatiotemporal pathways leading to the spheroidization of cementite. A change in the evolution mechanism from the ‘edge-migration regime ’ to a ‘discontinuities-assisted’ one, is found to be responsible for the fragmentation of cementite plates. The influence of the kinetic pathways on the resulting size and spatial distribution of the spheroids are discussed.
KW - Capillarity journal: acta materialia
KW - Pearlite
KW - Phase-field modeling
KW - Spheroidization
KW - Subcritical annealing
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U2 - 10.1016/j.actamat.2018.09.043
DO - 10.1016/j.actamat.2018.09.043
M3 - Article
AN - SCOPUS:85054055486
SN - 1359-6454
VL - 161
SP - 400
EP - 411
JO - Acta Materialia
JF - Acta Materialia
ER -