TY - JOUR
T1 - Mechanisms of localized pulsed electrodeposition (L-PED) for microscale 3D printing of nanotwinned metals
AU - Morsali, Reza
AU - Qian, Dong
AU - Minary-Jolandan, Majid
N1 - Funding Information:
This work was supported by the NSF-CMMI (award # 1727539), the US Office of Naval Research (award # N00014-15-1-2795), and NASA-SBIR award No. 80NSSC18P2193 subcontract from NANORANCH company.
Publisher Copyright:
© The Electrochemical Society
PY - 2019
Y1 - 2019
N2 - Nanotwinned metals (nt-metals) show larger ductility and strength compared to nanocrystalline metals facilitated by their special microstructure containing arrays of parallel twin boundaries. The recently-introduced localized pulsed electrodeposition (L-PED) enables 3D printing of nt-metals in complex geometries. Herein, the first computational model incorporating all the involved physics (i.e. electrodeposition, evaporation, fluid flow, and heat transfer) in the L-PED process is presented. The model reveals the critical rules of the pulsed signal and evaporation-driven convection flux in the mass transport mechanism, ion concentration, current density, and printing rate in the L-PED process. Notably, the simulation results predict a very high peak current density (∼130 times of the average current density) during the short (∼ms) ON-time. This high current density in a short period of ON-time results in high deposition rate, of possibly a metal with high internal stress. This prediction may explain the current hypotheses in the literature on formation of nt-metals by stress relaxation during the OFF-time.
AB - Nanotwinned metals (nt-metals) show larger ductility and strength compared to nanocrystalline metals facilitated by their special microstructure containing arrays of parallel twin boundaries. The recently-introduced localized pulsed electrodeposition (L-PED) enables 3D printing of nt-metals in complex geometries. Herein, the first computational model incorporating all the involved physics (i.e. electrodeposition, evaporation, fluid flow, and heat transfer) in the L-PED process is presented. The model reveals the critical rules of the pulsed signal and evaporation-driven convection flux in the mass transport mechanism, ion concentration, current density, and printing rate in the L-PED process. Notably, the simulation results predict a very high peak current density (∼130 times of the average current density) during the short (∼ms) ON-time. This high current density in a short period of ON-time results in high deposition rate, of possibly a metal with high internal stress. This prediction may explain the current hypotheses in the literature on formation of nt-metals by stress relaxation during the OFF-time.
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U2 - 10.1149/2.0051910jes
DO - 10.1149/2.0051910jes
M3 - Article
AN - SCOPUS:85073262363
SN - 0013-4651
VL - 166
SP - D354-D358
JO - Journal of the Electrochemical Society
JF - Journal of the Electrochemical Society
IS - 8
ER -