Abstract
The extraordinary structural properties of graphene and carbon nanotube materials motivate the development of practical methods for their use in fabricating continuous, strong, and tough composite fibers. Poly(vinyl alcohol) (PVA)/carbon nano-chip fiber (CNCF) composite tapes with 0.5 wt % loading show that Young's modulus, tensile strength, and toughness are increased by 585%, 653%, and 20%, respectively as compared to the control (PVA) tapes. Nano-chips exfoliated from the CNCF during processing, lubricate polymer chain alignment, and orientation during drawing, where composite tapes could be drawn to higher draw ratios compared with the control tapes. As a result, the Herman's orientation factor (f) increased from 0.5 (control tape) to 0.8 (composite tape). Theoretical analysis shows ∼ 16 vol % of the composite tapes consists of fully oriented PVA chains, which contributes to its exceptional mechanical performance. © 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013
| Original language | English (US) |
|---|---|
| Pages (from-to) | 2977-2982 |
| Number of pages | 6 |
| Journal | Journal of Applied Polymer Science |
| Volume | 127 |
| Issue number | 4 |
| DOIs | |
| State | Published - Feb 15 2013 |
| Externally published | Yes |
Keywords
- PVA
- crystallinity
- fibers
- nano-composites
- nanotubes
- tapes
ASJC Scopus subject areas
- General Chemistry
- Surfaces, Coatings and Films
- Polymers and Plastics
- Materials Chemistry