Laser-induced fluorescence and microwave-optical double-resonance study of the B1Σ+-X1Σ+ system of magnesium monoxide

Yoshiro Azuma, Thomas R. Dyke, Gretchen K. Gerke, Timothy Steimle

Research output: Contribution to journalArticle

12 Citations (Scopus)

Abstract

Doppler-limited, laser-induced fluorescence spectra on the B1Σ+-X1Σ+ (v′ = v″ = 0 and 1) system of MgO have been obtained. The results of the optical analysis were merged with our microwave-optical double-resonance measurements to produce the following set of spectroscopic parameters for the B and X states, where the units are in cm-1, and the uncertainties represent 95% confidence limits: T′0.0 = 20003.594(2); B′0 = 0.58004(3); D′0 = 1.13(2) × 10-6; B″0 = 0.57198(3); D″0 = 1.20(2) × 106; T′1.1 = 20043.423(2); B′1 = 0.57528(4); D′1 = 1.14(11) × 106; B″1 = 0.56674(4); D″1 = 1.22(10) × 106.

Original languageEnglish (US)
Pages (from-to)137-142
Number of pages6
JournalJournal of Molecular Spectroscopy
Volume108
Issue number1
DOIs
StatePublished - 1984
Externally publishedYes

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confidence limits
laser induced fluorescence
Magnesium
magnesium
Fluorescence
Microwaves
microwaves
Lasers
Uncertainty

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Spectroscopy
  • Atomic and Molecular Physics, and Optics

Cite this

Laser-induced fluorescence and microwave-optical double-resonance study of the B1Σ+-X1Σ+ system of magnesium monoxide. / Azuma, Yoshiro; Dyke, Thomas R.; Gerke, Gretchen K.; Steimle, Timothy.

In: Journal of Molecular Spectroscopy, Vol. 108, No. 1, 1984, p. 137-142.

Research output: Contribution to journalArticle

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title = "Laser-induced fluorescence and microwave-optical double-resonance study of the B1Σ+-X1Σ+ system of magnesium monoxide",
abstract = "Doppler-limited, laser-induced fluorescence spectra on the B1Σ+-X1Σ+ (v′ = v″ = 0 and 1) system of MgO have been obtained. The results of the optical analysis were merged with our microwave-optical double-resonance measurements to produce the following set of spectroscopic parameters for the B and X states, where the units are in cm-1, and the uncertainties represent 95{\%} confidence limits: T′0.0 = 20003.594(2); B′0 = 0.58004(3); D′0 = 1.13(2) × 10-6; B″0 = 0.57198(3); D″0 = 1.20(2) × 106; T′1.1 = 20043.423(2); B′1 = 0.57528(4); D′1 = 1.14(11) × 106; B″1 = 0.56674(4); D″1 = 1.22(10) × 106.",
author = "Yoshiro Azuma and Dyke, {Thomas R.} and Gerke, {Gretchen K.} and Timothy Steimle",
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T1 - Laser-induced fluorescence and microwave-optical double-resonance study of the B1Σ+-X1Σ+ system of magnesium monoxide

AU - Azuma, Yoshiro

AU - Dyke, Thomas R.

AU - Gerke, Gretchen K.

AU - Steimle, Timothy

PY - 1984

Y1 - 1984

N2 - Doppler-limited, laser-induced fluorescence spectra on the B1Σ+-X1Σ+ (v′ = v″ = 0 and 1) system of MgO have been obtained. The results of the optical analysis were merged with our microwave-optical double-resonance measurements to produce the following set of spectroscopic parameters for the B and X states, where the units are in cm-1, and the uncertainties represent 95% confidence limits: T′0.0 = 20003.594(2); B′0 = 0.58004(3); D′0 = 1.13(2) × 10-6; B″0 = 0.57198(3); D″0 = 1.20(2) × 106; T′1.1 = 20043.423(2); B′1 = 0.57528(4); D′1 = 1.14(11) × 106; B″1 = 0.56674(4); D″1 = 1.22(10) × 106.

AB - Doppler-limited, laser-induced fluorescence spectra on the B1Σ+-X1Σ+ (v′ = v″ = 0 and 1) system of MgO have been obtained. The results of the optical analysis were merged with our microwave-optical double-resonance measurements to produce the following set of spectroscopic parameters for the B and X states, where the units are in cm-1, and the uncertainties represent 95% confidence limits: T′0.0 = 20003.594(2); B′0 = 0.58004(3); D′0 = 1.13(2) × 10-6; B″0 = 0.57198(3); D″0 = 1.20(2) × 106; T′1.1 = 20043.423(2); B′1 = 0.57528(4); D′1 = 1.14(11) × 106; B″1 = 0.56674(4); D″1 = 1.22(10) × 106.

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