Large-scale homogeneous molecular templates for femtosecond time-resolved studies of the guest-host interaction

P. Siffalovic; M. Michelswirth; P. Bartz; B. Decker; C. Agena; C. Schäfer; S. Molter; R. Ros; M. Bach; M. Neumann; D. Anselmetti; J. Mattay; U. Heinzmann; M. Drescher

doi:10.1016/j.jbiotec.2004.04.023

Large-scale homogeneous molecular templates for femtosecond time-resolved studies of the guest-host interaction

P. Siffalovic, M. Michelswirth, P. Bartz, B. Decker, C. Agena, C. Schäfer, S. Molter, R. Ros, M. Bach, M. Neumann, D. Anselmetti, J. Mattay, U. Heinzmann, M. Drescher

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

Self-assembled monolayer films based on iodobenzoyloxy-functionalized resorc[4]arenes were prepared on gold substrates to serve as model systems for future time-resolved studies of molecular recognition, a mechanism of outstanding importance in bioorganic systems. The film properties were tested using X-ray photoelectron spectroscopy (XPS), atomic force microscopy (AFM) and imaging ellipsometry. An apparatus for time-resolved electron spectroscopy utilizing femtosecond soft X-ray pulses is capable of detecting iodine core-level photolines and the photoinduced dissociation after ultraviolet illumination. The developed technique holds promise for tracking the temporal evolution of chemical shifts of atomic markers as local probes for the dynamics of the guest-host interaction.

Original language	English (US)
Pages (from-to)	139-149
Number of pages	11
Journal	Journal of Biotechnology
Volume	112
Issue number	1-2
DOIs	https://doi.org/10.1016/j.jbiotec.2004.04.023
State	Published - Aug 26 2004
Externally published	Yes

Keywords

Guest-host interaction
Molecular dynamics
Molecular recognition
Self-assembled monolayer

ASJC Scopus subject areas

Biotechnology
Bioengineering
Applied Microbiology and Biotechnology

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10.1016/j.jbiotec.2004.04.023

Cite this

Siffalovic, P., Michelswirth, M., Bartz, P., Decker, B., Agena, C., Schäfer, C., Molter, S., Ros, R., Bach, M., Neumann, M., Anselmetti, D., Mattay, J., Heinzmann, U., & Drescher, M. (2004). Large-scale homogeneous molecular templates for femtosecond time-resolved studies of the guest-host interaction. Journal of Biotechnology, 112(1-2), 139-149. https://doi.org/10.1016/j.jbiotec.2004.04.023

Siffalovic, P, Michelswirth, M, Bartz, P, Decker, B, Agena, C, Schäfer, C, Molter, S, Ros, R, Bach, M, Neumann, M, Anselmetti, D, Mattay, J, Heinzmann, U & Drescher, M 2004, 'Large-scale homogeneous molecular templates for femtosecond time-resolved studies of the guest-host interaction', Journal of Biotechnology, vol. 112, no. 1-2, pp. 139-149. https://doi.org/10.1016/j.jbiotec.2004.04.023

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title = "Large-scale homogeneous molecular templates for femtosecond time-resolved studies of the guest-host interaction",

abstract = "Self-assembled monolayer films based on iodobenzoyloxy-functionalized resorc[4]arenes were prepared on gold substrates to serve as model systems for future time-resolved studies of molecular recognition, a mechanism of outstanding importance in bioorganic systems. The film properties were tested using X-ray photoelectron spectroscopy (XPS), atomic force microscopy (AFM) and imaging ellipsometry. An apparatus for time-resolved electron spectroscopy utilizing femtosecond soft X-ray pulses is capable of detecting iodine core-level photolines and the photoinduced dissociation after ultraviolet illumination. The developed technique holds promise for tracking the temporal evolution of chemical shifts of atomic markers as local probes for the dynamics of the guest-host interaction.",

keywords = "Guest-host interaction, Molecular dynamics, Molecular recognition, Self-assembled monolayer",

author = "P. Siffalovic and M. Michelswirth and P. Bartz and B. Decker and C. Agena and C. Sch{\"a}fer and S. Molter and R. Ros and M. Bach and M. Neumann and D. Anselmetti and J. Mattay and U. Heinzmann and M. Drescher",

note = "Funding Information: We are indebted to A. Brechling and U. Kleineberg for supporting us in the UV-patterning and ellipsometry measurements. We gratefully acknowledge the support by the Deutsche Forschungsgemeinschaft. ",

year = "2004",

month = aug,

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doi = "10.1016/j.jbiotec.2004.04.023",

language = "English (US)",

volume = "112",

pages = "139--149",

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T1 - Large-scale homogeneous molecular templates for femtosecond time-resolved studies of the guest-host interaction

AU - Siffalovic, P.

AU - Michelswirth, M.

AU - Bartz, P.

AU - Decker, B.

AU - Agena, C.

AU - Schäfer, C.

AU - Molter, S.

AU - Ros, R.

AU - Bach, M.

AU - Neumann, M.

AU - Anselmetti, D.

AU - Mattay, J.

AU - Heinzmann, U.

AU - Drescher, M.

N1 - Funding Information: We are indebted to A. Brechling and U. Kleineberg for supporting us in the UV-patterning and ellipsometry measurements. We gratefully acknowledge the support by the Deutsche Forschungsgemeinschaft.

PY - 2004/8/26

Y1 - 2004/8/26

N2 - Self-assembled monolayer films based on iodobenzoyloxy-functionalized resorc[4]arenes were prepared on gold substrates to serve as model systems for future time-resolved studies of molecular recognition, a mechanism of outstanding importance in bioorganic systems. The film properties were tested using X-ray photoelectron spectroscopy (XPS), atomic force microscopy (AFM) and imaging ellipsometry. An apparatus for time-resolved electron spectroscopy utilizing femtosecond soft X-ray pulses is capable of detecting iodine core-level photolines and the photoinduced dissociation after ultraviolet illumination. The developed technique holds promise for tracking the temporal evolution of chemical shifts of atomic markers as local probes for the dynamics of the guest-host interaction.

AB - Self-assembled monolayer films based on iodobenzoyloxy-functionalized resorc[4]arenes were prepared on gold substrates to serve as model systems for future time-resolved studies of molecular recognition, a mechanism of outstanding importance in bioorganic systems. The film properties were tested using X-ray photoelectron spectroscopy (XPS), atomic force microscopy (AFM) and imaging ellipsometry. An apparatus for time-resolved electron spectroscopy utilizing femtosecond soft X-ray pulses is capable of detecting iodine core-level photolines and the photoinduced dissociation after ultraviolet illumination. The developed technique holds promise for tracking the temporal evolution of chemical shifts of atomic markers as local probes for the dynamics of the guest-host interaction.

KW - Guest-host interaction

KW - Molecular dynamics

KW - Molecular recognition

KW - Self-assembled monolayer

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M3 - Article

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JO - Journal of Biotechnology

JF - Journal of Biotechnology

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ER -

Large-scale homogeneous molecular templates for femtosecond time-resolved studies of the guest-host interaction

Abstract

Keywords

ASJC Scopus subject areas

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