Ionomer design for augmented charge transport in novel ionic polymer transducers

Andrew J. Duncan, Donald J. Leo, Timothy E. Long, Barbar J. Akle, Stephen A. Sarles

Research output: Chapter in Book/Report/Conference proceedingConference contribution

1 Scopus citations

Abstract

Ionic polymer transducers (IPT) are devices that display electromechanical transduction and have been applied extensively both as actuators and sensors. This study employs novel, highly-branched sulfonated polysulfones to investigate the contribution of polymer topology to electromechanical transduction. We assess two methods for ionic liquid uptake in the central ionomeric membrane. The effects of casting membranes in the presence of ionic liquid and swelling cast membranes in ionic liquid on film stability and ionic conductivity are examined. Casting in the presence of ionic liquid appears to cause macrophase separation of the ionic liquid from the polymer, causing limited charge transport. Overall, swelling appears to be a more stable method and achieves higher conductivity at lower uptake levels.

Original languageEnglish (US)
Title of host publicationProceedings of the ASME Conference on Smart Materials, Adaptive Structures and Intelligent Systems, SMASIS2008
Pages121-129
Number of pages9
DOIs
StatePublished - 2008
Externally publishedYes
EventASME Conference on Smart Materials, Adaptive Structures and Intelligent Systems, SMASIS2008 - Ellicott City, MD, United States
Duration: Oct 28 2008Oct 30 2008

Publication series

NameProceedings of the ASME Conference on Smart Materials, Adaptive Structures and Intelligent Systems, SMASIS2008
Volume1

Other

OtherASME Conference on Smart Materials, Adaptive Structures and Intelligent Systems, SMASIS2008
Country/TerritoryUnited States
CityEllicott City, MD
Period10/28/0810/30/08

ASJC Scopus subject areas

  • Civil and Structural Engineering
  • Control and Systems Engineering
  • Mechanics of Materials
  • Building and Construction

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