Investigation of the capacity decay of a CdO-NaI mixed sorbent for pre-combustion CO2 capture

Christian Vogt, Thomas R. Gengenbach, Lan-Yun Chang, Gregory P. Knowles, Alan L. Chaffee

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

The mechanisms for the loss of both CO2 working capacity and mass from a CdO-NaI composite were investigated to better assess the potential use of the material to facilitate the pre-combustion capture of CO2 from syngas. Fresh activated material was used to analyse sorption and desorption using a CO2-N2 mixture. Mass spectrometric analysis of the exit gas revealed the loss of elemental iodine from the system over the period, attributed to the oxidation of iodide. Thermogravimetric analysis using iodine vapour suggested the iodide loss reaction to be a partially reversible equilibrium. X-ray photoelectron spectroscopy revealed the formation of a highly oxidised iodine species on the surface of the sorbent during initial calcination in both air and N2, but this compound vanished after the use of the sorbent in 25 CO2 sorption cycles. Elemental mapping showed that iodine was dislocated from the sodium, which it was considered to be originally associated to, supporting the theory of oxidation and evaporation (and possible re-deposition). Transmission electron microscopy revealed that the sorbent consisted of regular, spherical nanoparticles of approx. 250 nm diameter, which became more irregularly-shaped after CO2 sorption cycles, considered to be due to void/crack formation caused by density changes upon calcination and carbonation. In situ powder X-ray diffraction revealed an increase in crystallinity of both CdO and NaI upon heating to CO2 sorption temperature of 325 °C in N2 atmosphere, compared to room temperature. If the oxidation of the iodide promoter can be inhibited, this is likely to improve the multicyclic CO2 sorption stability of this material for future use. This journal is

Original languageEnglish (US)
Pages (from-to)5162-5175
Number of pages14
JournalJournal of Materials Chemistry A
Volume3
Issue number9
DOIs
StatePublished - Mar 7 2015
Externally publishedYes

Fingerprint

Sorbents
Sorption
Iodine
Iodides
Oxidation
Calcination
Carbonation
Crack initiation
X ray powder diffraction
Thermogravimetric analysis
Desorption
Evaporation
X ray photoelectron spectroscopy
Gases
Sodium
Vapors
Nanoparticles
Transmission electron microscopy
Heating
Temperature

ASJC Scopus subject areas

  • Chemistry(all)
  • Renewable Energy, Sustainability and the Environment
  • Materials Science(all)

Cite this

Investigation of the capacity decay of a CdO-NaI mixed sorbent for pre-combustion CO2 capture. / Vogt, Christian; Gengenbach, Thomas R.; Chang, Lan-Yun; Knowles, Gregory P.; Chaffee, Alan L.

In: Journal of Materials Chemistry A, Vol. 3, No. 9, 07.03.2015, p. 5162-5175.

Research output: Contribution to journalArticle

Vogt, Christian ; Gengenbach, Thomas R. ; Chang, Lan-Yun ; Knowles, Gregory P. ; Chaffee, Alan L. / Investigation of the capacity decay of a CdO-NaI mixed sorbent for pre-combustion CO2 capture. In: Journal of Materials Chemistry A. 2015 ; Vol. 3, No. 9. pp. 5162-5175.
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