In situ observation of the growth mechanisms of carbon nanotubes under diverse reaction conditions

Renu Sharma, Peter Rez, Michael Treacy, Steven J. Stuart

Research output: Contribution to journalArticle

65 Citations (Scopus)

Abstract

We report in situ environmental transmission electron microscope observations of the nucleation and growth of multi-wall and single-wall carbon nanotubes formed by the catalytic decomposition of acetylene (C2H2) on Ni/SiO2 catalyst. The growth rate, structure and morphology of the carbon nanotubes formed depended upon reaction temperature and pressure. Under 20-100 mTorr of gas pressures at 480°C, serpentine-shaped or zigzag, multi-wall carbon nanotubes grew at an average rate of 35-40 nm sec -1. At pressures <10 mTorr at the same temperature, straight single-wall carbon nanotubes with nearly uniform diameters (∼3.5 nm) formed at average growth rates of 6-9 nm sec-1. The growth of both straight and serpentine carbon nanotubes tends to proceed at non-uniform rates, with frequent pauses followed by growth spurts. The nanotubes frequently contained sharp bends that turned the nanotube axis by ∼60° and ∼120°. We conjecture that the bends are related to the change in growth direction that is dictated by the crystallographic orientation of the catalyst particle. The rotations of the nanometer-sized catalyst particle may be caused by transient melting-recrystallization events caused by local thermal variations. The nanotube attempts to follow the preferred growth direction, while simultaneously attempting to maintain a seamless 3-coordinated graphene wall. This latter condition is most easily satisfied by the introduction of pentagon-heptagon defect pairs dissociated to the opposite sides of the nanotube creating the 60° bend.

Original languageEnglish (US)
Pages (from-to)231-237
Number of pages7
JournalJournal of Electron Microscopy
Volume54
Issue number3
DOIs
StatePublished - Jun 2005

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Carbon Nanotubes
Carbon nanotubes
carbon nanotubes
Nanotubes
Observation
Growth
nanotubes
Catalysts
Pressure
catalysts
Acetylene
Graphene
Temperature
Graphite
Melting
Nucleation
Electron microscopes
acetylene
Decomposition
Freezing

Keywords

  • Carbon nanotubes
  • Catalyst
  • Chemical vapor deposition
  • Environmental transmission electron microscope
  • Growth mechanisms
  • In situ

ASJC Scopus subject areas

  • Instrumentation

Cite this

In situ observation of the growth mechanisms of carbon nanotubes under diverse reaction conditions. / Sharma, Renu; Rez, Peter; Treacy, Michael; Stuart, Steven J.

In: Journal of Electron Microscopy, Vol. 54, No. 3, 06.2005, p. 231-237.

Research output: Contribution to journalArticle

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