Fundamental Limitations on the Low-Temperature Operation of Electrolytic Devices

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Abstract

A new approach to the understanding of transport behavior in concentrated electrolyte solutions requires the recognition at low temperatures of a liquid state limiting temperature which is a thermodynamic constant of any solvent-electrolyte solution. The value of this constant, which determines service limits, is a function of electrolyte concentration except at low concentrations where solvent structure may dominate. In this paper the results of workers investigating electrolyte solutions for low-temperature battery applications are used to emphasize the usefulness of the concepts underlying this approach to low-temperature electrolyte problems.

Original languageEnglish (US)
Pages (from-to)1033-1035
Number of pages3
JournalJournal of the Electrochemical Society
Volume114
Issue number10
DOIs
StatePublished - Oct 1967

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ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Renewable Energy, Sustainability and the Environment
  • Surfaces, Coatings and Films
  • Electrochemistry
  • Materials Chemistry

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