TY - JOUR
T1 - From Simple Electrolyte Solutions Through Polymer Electrolytes to Superionic Rubbers
T2 - Some Fundamental Considerations
AU - Angell, Charles
AU - Imrie, Corrie T.
AU - Ingram, Malcolm D.
PY - 1998
Y1 - 1998
N2 - A general discussion is presented for the conductivity-viscosity and viscosity-temperature relationships in polymer electrolytes in the context of systematizing the efforts to obtain higher ionic conductivities at ambient temperatures. Topics discussed include: the Walden rule, glass-rubber and rubber-melt transitions, the strength-fragility concept, the Vogel-Fulcher-Tammann and Williams-Landel-Ferry equations, the chelation effect and the decoupling of ionic transport from the structural relaxation processes.
AB - A general discussion is presented for the conductivity-viscosity and viscosity-temperature relationships in polymer electrolytes in the context of systematizing the efforts to obtain higher ionic conductivities at ambient temperatures. Topics discussed include: the Walden rule, glass-rubber and rubber-melt transitions, the strength-fragility concept, the Vogel-Fulcher-Tammann and Williams-Landel-Ferry equations, the chelation effect and the decoupling of ionic transport from the structural relaxation processes.
KW - Decoupling effects
KW - Polymer electrolytes
KW - Transport mechanisms
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U2 - 10.1002/(sici)1097-0126(199809)47:1<9::aid-pi69>3.0.co;2-1
DO - 10.1002/(sici)1097-0126(199809)47:1<9::aid-pi69>3.0.co;2-1
M3 - Article
AN - SCOPUS:0032154866
SN - 0959-8103
VL - 47
SP - 9
EP - 15
JO - Polymer International
JF - Polymer International
IS - 1
ER -