Dual Metal Active Sites in an Ir1/FeOx Single-Atom Catalyst: A Redox Mechanism for the Water-Gas Shift Reaction

Jin Xia Liang, Jian Lin, Jingyue Liu, Xiaodong Wang, Tao Zhang, Jun Li

Research output: Contribution to journalArticle

3 Scopus citations

Abstract

Herein, we report a theoretical and experimental study of the water-gas shift (WGS) reaction on Ir1/FeOx single-atom catalysts. Water dissociates to OH* on the Ir1 single atom and H* on the first-neighbour O atom bonded with a Fe site. The adsorbed CO on Ir1 reacts with another adjacent O atom to produce CO2, yielding an oxygen vacancy (Ovac). Then, the formation of H2 becomes feasible due to migration of H from adsorbed OH* toward Ir1 and its subsequent reaction with another H*. The interaction of Ir1 and the second-neighbouring Fe species demonstrates a new WGS pathway featured by electron transfer at the active site from Fe3+−O⋅⋅⋅Ir2+−Ovac to Fe2+−Ovac⋅⋅⋅Ir3+−O with the involvement of Ovac. The redox mechanism for WGS reaction through a dual metal active site (DMAS) is different from the conventional associative mechanism with the formation of formate or carboxyl intermediates. The proposed new reaction mechanism is corroborated by the experimental results with Ir1/FeOx for sequential production of CO2 and H2.

Original languageEnglish (US)
Pages (from-to)12868-12875
Number of pages8
JournalAngewandte Chemie - International Edition
Volume59
Issue number31
DOIs
StatePublished - Jul 27 2020

Keywords

  • active sites
  • density functional theory
  • redox mechanism
  • single-atom catalysts
  • water-gas shift reaction

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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