Direct Observation of Gate-Tunable Dark Trions in Monolayer WSe2

Zhipeng Li, Tianmeng Wang, Zhengguang Lu, Mandeep Khatoniar, Zhen Lian, Yuze Meng, Mark Blei, Takashi Taniguchi, Kenji Watanabe, Stephen A. McGill, Sefaattin Tongay, Vinod M. Menon, Dmitry Smirnov, Su Fei Shi

Research output: Contribution to journalArticle

Abstract

Spin-forbidden intravalley dark excitons in tungsten-based transition-metal dichalcogenides (TMDCs), because of their unique spin texture and long lifetime, have attracted intense research interest. Here, we show that we can control the dark exciton electrostatically by dressing it with one free electron or free hole, forming the dark trions. The existence of the dark trions is suggested by the unique magneto-photoluminescence spectroscopy pattern of the boron nitride (BN)-encapsulated monolayer WSe2 device at low temperature. The unambiguous evidence of the dark trions is further obtained by directly resolving the radiation pattern of the dark trions through back focal plane imaging. The dark trions possess a binding energy of ∼15 meV, and they inherit the long lifetime and large g-factor from the dark exciton. Interestingly, under the out-of-plane magnetic field, dressing the dark exciton with one free electron or hole results in distinctively different valley polarization of the emitted photon, as a result of the different intervalley scattering mechanism for the electron and hole. Finally, the lifetime of the positive dark trion can be further tuned from ∼50 ps to ∼215 ps by controlling the gate voltage. The gate-tunable dark trions usher in new opportunities for excitonic optoelectronics and valleytronics.

Original languageEnglish (US)
Pages (from-to)6886-6893
Number of pages8
JournalNano Letters
Volume19
Issue number10
DOIs
StatePublished - Oct 9 2019

Fingerprint

Excitons
Monolayers
excitons
life (durability)
free electrons
Electrons
Tungsten
Photoluminescence spectroscopy
Boron nitride
boron nitrides
Binding energy
Optoelectronic devices
Transition metals
valleys
tungsten
Photons
textures
Textures
binding energy
transition metals

Keywords

  • dark trion
  • Fourier plane imaging
  • magneto-PL
  • TRPL
  • valley polarization

ASJC Scopus subject areas

  • Bioengineering
  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics
  • Mechanical Engineering

Cite this

Li, Z., Wang, T., Lu, Z., Khatoniar, M., Lian, Z., Meng, Y., ... Shi, S. F. (2019). Direct Observation of Gate-Tunable Dark Trions in Monolayer WSe2 Nano Letters, 19(10), 6886-6893. https://doi.org/10.1021/acs.nanolett.9b02132

Direct Observation of Gate-Tunable Dark Trions in Monolayer WSe2 . / Li, Zhipeng; Wang, Tianmeng; Lu, Zhengguang; Khatoniar, Mandeep; Lian, Zhen; Meng, Yuze; Blei, Mark; Taniguchi, Takashi; Watanabe, Kenji; McGill, Stephen A.; Tongay, Sefaattin; Menon, Vinod M.; Smirnov, Dmitry; Shi, Su Fei.

In: Nano Letters, Vol. 19, No. 10, 09.10.2019, p. 6886-6893.

Research output: Contribution to journalArticle

Li, Z, Wang, T, Lu, Z, Khatoniar, M, Lian, Z, Meng, Y, Blei, M, Taniguchi, T, Watanabe, K, McGill, SA, Tongay, S, Menon, VM, Smirnov, D & Shi, SF 2019, 'Direct Observation of Gate-Tunable Dark Trions in Monolayer WSe2 ', Nano Letters, vol. 19, no. 10, pp. 6886-6893. https://doi.org/10.1021/acs.nanolett.9b02132
Li Z, Wang T, Lu Z, Khatoniar M, Lian Z, Meng Y et al. Direct Observation of Gate-Tunable Dark Trions in Monolayer WSe2 Nano Letters. 2019 Oct 9;19(10):6886-6893. https://doi.org/10.1021/acs.nanolett.9b02132
Li, Zhipeng ; Wang, Tianmeng ; Lu, Zhengguang ; Khatoniar, Mandeep ; Lian, Zhen ; Meng, Yuze ; Blei, Mark ; Taniguchi, Takashi ; Watanabe, Kenji ; McGill, Stephen A. ; Tongay, Sefaattin ; Menon, Vinod M. ; Smirnov, Dmitry ; Shi, Su Fei. / Direct Observation of Gate-Tunable Dark Trions in Monolayer WSe2 In: Nano Letters. 2019 ; Vol. 19, No. 10. pp. 6886-6893.
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