Diffusion-conductance relations and free volume in molten salts

Research output: Contribution to journalArticle

14 Scopus citations

Abstract

Departures from the Nernst-Einstein equation for a variety of pure molten salts are correlated by means of "glass transition-based" corresponding temperatures suggested by a recent free volume model of transport in molten salts. Coupled with molar volume data, these correlations are consistent with the view that mutual ionic interference, rather than paired vacancy diffusion, causes the breakdown of the Nernst-Einstein equation in these liquids.

Original languageEnglish (US)
Pages (from-to)399-403
Number of pages5
JournalJournal of physical chemistry
Volume69
Issue number2
DOIs
StatePublished - Jan 1 1965
Externally publishedYes

ASJC Scopus subject areas

  • Engineering(all)
  • Physical and Theoretical Chemistry

Fingerprint Dive into the research topics of 'Diffusion-conductance relations and free volume in molten salts'. Together they form a unique fingerprint.

  • Cite this