Diffusion-conductance relations and free volume in molten salts

Research output: Contribution to journalArticle

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Abstract

Departures from the Nernst-Einstein equation for a variety of pure molten salts are correlated by means of "glass transition-based" corresponding temperatures suggested by a recent free volume model of transport in molten salts. Coupled with molar volume data, these correlations are consistent with the view that mutual ionic interference, rather than paired vacancy diffusion, causes the breakdown of the Nernst-Einstein equation in these liquids.

Original languageEnglish (US)
Pages (from-to)399-403
Number of pages5
JournalJournal of Physical Chemistry
Volume69
Issue number2
StatePublished - 1965
Externally publishedYes

Fingerprint

molten salts
Free volume
Einstein equations
Molten materials
Salts
data correlation
Density (specific gravity)
Vacancies
Glass transition
breakdown
interference
glass
causes
Liquids
liquids
Temperature
temperature

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry

Cite this

Diffusion-conductance relations and free volume in molten salts. / Angell, Charles.

In: Journal of Physical Chemistry, Vol. 69, No. 2, 1965, p. 399-403.

Research output: Contribution to journalArticle

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