Diffusion-conductance relations and free volume in molten salts

C. A. Angell

doi:10.1021/j100886a007

Diffusion-conductance relations and free volume in molten salts

C. A. Angell

Research output: Contribution to journal › Article › peer-review

16 Scopus citations

Abstract

Departures from the Nernst-Einstein equation for a variety of pure molten salts are correlated by means of "glass transition-based" corresponding temperatures suggested by a recent free volume model of transport in molten salts. Coupled with molar volume data, these correlations are consistent with the view that mutual ionic interference, rather than paired vacancy diffusion, causes the breakdown of the Nernst-Einstein equation in these liquids.

Original language	English (US)
Pages (from-to)	399-403
Number of pages	5
Journal	Journal of physical chemistry
Volume	69
Issue number	2
DOIs	https://doi.org/10.1021/j100886a007
State	Published - Jan 1 1965
Externally published	Yes

ASJC Scopus subject areas

Engineering(all)
Physical and Theoretical Chemistry

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10.1021/j100886a007

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AB - Departures from the Nernst-Einstein equation for a variety of pure molten salts are correlated by means of "glass transition-based" corresponding temperatures suggested by a recent free volume model of transport in molten salts. Coupled with molar volume data, these correlations are consistent with the view that mutual ionic interference, rather than paired vacancy diffusion, causes the breakdown of the Nernst-Einstein equation in these liquids.

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Diffusion-conductance relations and free volume in molten salts

Abstract

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