Coordination dependent vibrational properties of amorphous semiconductors alloys

G. Lucovsky; R. J. Nemanich; S. A. Solin; R. C. Keezer

doi:10.1016/0038-1098(75)90997-7

Coordination dependent vibrational properties of amorphous semiconductors alloys

G. Lucovsky, R. J. Nemanich, S. A. Solin, R. C. Keezer

Research output: Contribution to journal › Article › peer-review

87 Scopus citations

Abstract

The i.r., Raman and depolarization spectra of the amorphous pseudo-binary alloy systems (GeS₂)_1-χ(As₂S₃)_χ and (GeSe₂)_1-χ(As₂Se₃)_χ are reported here. In contrast to the one-mode behavior that is anticipated on the basis of the mass ratio of the alloy atoms (Ge/As), two bond-stretching modes are observed in both the i.r. and Raman spectra. This new type of phonon behavior is interpreted in terms of differences in the local coordination via a chemical bonding model.

Original language	English (US)
Pages (from-to)	1567-1572
Number of pages	6
Journal	Solid State Communications
Volume	17
Issue number	12
DOIs	https://doi.org/10.1016/0038-1098(75)90997-7
State	Published - Dec 15 1975
Externally published	Yes

ASJC Scopus subject areas

General Chemistry
Condensed Matter Physics
Materials Chemistry

Access to Document

10.1016/0038-1098(75)90997-7

Cite this

@article{a628c50db09b47c28dd24ef04c3b677f,

title = "Coordination dependent vibrational properties of amorphous semiconductors alloys",

abstract = "The i.r., Raman and depolarization spectra of the amorphous pseudo-binary alloy systems (GeS2)1-χ(As2S3)χ and (GeSe2)1-χ(As2Se3)χ are reported here. In contrast to the one-mode behavior that is anticipated on the basis of the mass ratio of the alloy atoms (Ge/As), two bond-stretching modes are observed in both the i.r. and Raman spectra. This new type of phonon behavior is interpreted in terms of differences in the local coordination via a chemical bonding model.",

author = "G. Lucovsky and Nemanich, {R. J.} and Solin, {S. A.} and Keezer, {R. C.}",

year = "1975",

month = dec,

day = "15",

doi = "10.1016/0038-1098(75)90997-7",

language = "English (US)",

volume = "17",

pages = "1567--1572",

journal = "Solid State Communications",

issn = "0038-1098",

publisher = "Elsevier Limited",

number = "12",

}

TY - JOUR

T1 - Coordination dependent vibrational properties of amorphous semiconductors alloys

AU - Lucovsky, G.

AU - Nemanich, R. J.

AU - Solin, S. A.

AU - Keezer, R. C.

PY - 1975/12/15

Y1 - 1975/12/15

N2 - The i.r., Raman and depolarization spectra of the amorphous pseudo-binary alloy systems (GeS2)1-χ(As2S3)χ and (GeSe2)1-χ(As2Se3)χ are reported here. In contrast to the one-mode behavior that is anticipated on the basis of the mass ratio of the alloy atoms (Ge/As), two bond-stretching modes are observed in both the i.r. and Raman spectra. This new type of phonon behavior is interpreted in terms of differences in the local coordination via a chemical bonding model.

AB - The i.r., Raman and depolarization spectra of the amorphous pseudo-binary alloy systems (GeS2)1-χ(As2S3)χ and (GeSe2)1-χ(As2Se3)χ are reported here. In contrast to the one-mode behavior that is anticipated on the basis of the mass ratio of the alloy atoms (Ge/As), two bond-stretching modes are observed in both the i.r. and Raman spectra. This new type of phonon behavior is interpreted in terms of differences in the local coordination via a chemical bonding model.

UR - http://www.scopus.com/inward/record.url?scp=0016643537&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0016643537&partnerID=8YFLogxK

U2 - 10.1016/0038-1098(75)90997-7

DO - 10.1016/0038-1098(75)90997-7

M3 - Article

AN - SCOPUS:0016643537

SN - 0038-1098

VL - 17

SP - 1567

EP - 1572

JO - Solid State Communications

JF - Solid State Communications

IS - 12

ER -

Coordination dependent vibrational properties of amorphous semiconductors alloys

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this