Abstract

Four methods, fast titration, salt addition, mass titration, and Χ potentiometry, were employed to determine the point of zero charge (PZC) and isoelectric point (IEP) of NiO. However, this work mainly focuses on the fast titration method because it limits the release of Ni from the substrate. Furthermore, the fast titration is simple, rapid, and accurate and requires a small quantity of substrate as compared to the salt addition and mass titration techniques. The similarity between the PZC and IEP values rules out the specific adsorption of the bulk electrolyte onto the NiO surface. However, the PZC values shift downward with the increase in Cd ion concentration, which indicates the specific adsorption of Cd onto the NiO. In addition, temperature has a mild effect on the deprotonation constants and PZC of NiO. It was also observed that the thermodynamic parameters favor the deprotonation of NiO.

Original languageEnglish (US)
Pages (from-to)10017-10023
Number of pages7
JournalIndustrial and Engineering Chemistry Research
Volume50
Issue number17
DOIs
StatePublished - Sep 7 2011

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Titration
Deprotonation
Salts
Adsorption
Substrates
Electrolytes
Thermodynamics
Ions
Temperature

ASJC Scopus subject areas

  • Chemical Engineering(all)
  • Chemistry(all)
  • Industrial and Manufacturing Engineering

Cite this

Comparison of different methods for the point of zero charge determination of NiO. / Mahmood, Tahira; Saddique, Muhammad Tahir; Naeem, Abdul; Westerhoff, Paul; Mustafa, Syed; Alum, Absar.

In: Industrial and Engineering Chemistry Research, Vol. 50, No. 17, 07.09.2011, p. 10017-10023.

Research output: Contribution to journalArticle

Mahmood, Tahira ; Saddique, Muhammad Tahir ; Naeem, Abdul ; Westerhoff, Paul ; Mustafa, Syed ; Alum, Absar. / Comparison of different methods for the point of zero charge determination of NiO. In: Industrial and Engineering Chemistry Research. 2011 ; Vol. 50, No. 17. pp. 10017-10023.
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AU - Alum, Absar

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