Combined removal of so2 and no using sol-gel-derived copper oxide coated alumina sorbents/catalysts

G. Buelna, Y. S. Lin

Research output: Contribution to journalArticle

6 Scopus citations

Abstract

The present paper reports experimental results on the removal of sulfur dioxide and nitrogen oxide from simulated flue gas using a copper oxide coated on alumina sorbent/catalyst prepared by the sol-gel method. Selective catalytic reduction of nitric oxide by ammonia over sol-gel derived CuO/y-Al2O3 sorbents/catalysts with different degrees of sulfation was studied in a fixed-bed packed reactor. The optimum temperature for NO reduction was found at 350°C for both fresh and sulfated catalysts. The properties for simultaneous removal of SO2 and NO by the sol-gel-derived CuO/γ-Al2O3 sorbents were studied using simulated dry flue gas. The optimum operating temperature for the combined deSO2/deNO operations was identified at 350°C. At the space velocity of 5200 h-1 and 350°C, a fixed-bed reactor packed with the 7.9 wt% CuO/γ-Al2O3 sorbent prepared by the sol-gel method offers SO2 Sorption capacity of 2.3 mmol g-1 and NO conversion of 92% with a dry simulated flue gas as the feed. Under these experimental conditions, the sol-gel derived sorbents/catalysts have comparable efficiency for removal of SO2 and NOX as their commercial counterparts. The significantly higher crush strength of the sol-gel derived sorbents/catalysts make them very promising for their use in the copper oxide process for combined removal of SO2 and NOx from flue gas in a single unit operation.

Original languageEnglish (US)
Pages (from-to)1087-1095
Number of pages9
JournalEnvironmental Technology (United Kingdom)
Volume24
Issue number9
DOIs
StatePublished - Sep 1 2003
Externally publishedYes

Keywords

  • Cuo
  • Deno
  • Deso
  • Selective catalytic reduction
  • γ-alo

ASJC Scopus subject areas

  • Environmental Chemistry
  • Water Science and Technology
  • Waste Management and Disposal

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