Characterization of CO2 flux through hollow-fiber membranes using pH modeling

Tarun Shesh, Everett Eustance, Yen Jung Lai, Bruce Rittmann

Research output: Contribution to journalArticle

Abstract

CO2 must be delivered efficiently during large-scale microalgal cultivation. Bubbleless mass-transfer via diffusion through hollow-fiber membranes (HFM) can achieve much higher CO2-transfer efficiency than traditional sparging systems. This study developed and used a model to compute accurate values for the CO2 flux (JCO2 ), overall mass-transfer coefficient (KL), and overall volumetric mass-transfer coefficient (KLa) based on the rate of change of pH in batch experiments. A composite HFM comprised of two macroporous polyethylene layers and a nonporous polyurethane layer was tested for CO2 transfer to a sodium carbonate solution using a range of total pressures, inlet CO2 concentrations, and open-end versus closed-end modes of operation. The model accurately computed JCO2 and KLa for pH values above 8. Key trends are that (i) JCO2 and KLa increased with increasing average inlet CO2 partial pressure; (ii) open-end HFMs performed better than closed-end HFMs when the supplied CO2 was less than 100%; and (iii) the available membrane area used for CO2 mass-transfer decreased as the inlet CO2 partial pressure decreased due to depletion of CO2 inside the membrane, especially for closed-end HFMs, since inert gases could not be vented.

Original languageEnglish (US)
Article number117389
JournalJournal of Membrane Science
Volume592
DOIs
StatePublished - Dec 15 2019

Fingerprint

inlet pressure
mass transfer
hollow
Mass transfer
Fluxes
membranes
Membranes
fibers
Fibers
Partial Pressure
Partial pressure
partial pressure
sodium carbonates
Noble Gases
Polyurethanes
Polyethylene
coefficients
Inert gases
Polyethylenes
polyethylenes

Keywords

  • CO delivery
  • Hollow fiber membrane
  • Mathematical modelling
  • Membrane carbonation

ASJC Scopus subject areas

  • Biochemistry
  • Materials Science(all)
  • Physical and Theoretical Chemistry
  • Filtration and Separation

Cite this

Characterization of CO2 flux through hollow-fiber membranes using pH modeling. / Shesh, Tarun; Eustance, Everett; Lai, Yen Jung; Rittmann, Bruce.

In: Journal of Membrane Science, Vol. 592, 117389, 15.12.2019.

Research output: Contribution to journalArticle

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