TY - GEN
T1 - Artificial photosynthesis
T2 - 235th National Meeting of the American Chemical Society, ACS 2008
AU - Moore, Thomas
AU - Moore, Ana
AU - Gust, Devens
AU - Hambourger, Michael
AU - Moore, Gary
AU - Keirstead, Amy
AU - Gervaldo, Miguel
PY - 2008
Y1 - 2008
N2 - Provided significant challenges can be met, solar powered, bio-inspired constructs can contribute to renewable energy resources to meet human energy needs. The central challenge is reversing the combustion process by efficient water oxidation and reductive synthesis of CO2 to fuels. Nature's catalysts direct these oxidation/reduction reactions along coordinates that have low activation barriers and almost no side reactions. In principle, these reactions can be driven by electricity provided by sustainable sources. In order to accomplish this, it will be necessary to switch nature's catalysts from their usual source of redox potential - electron/proton carrying redox species - to emf at appropriate electrical potentials. Taking a step in this direction, we have assembled a hybrid system in which a porphyrin-sensitized Grätzel-type nanoparticulate wide band gap semiconductor photoanode is used as an interface between emf and redox potential for the photochemical reformation of biomass to hydrogen.
AB - Provided significant challenges can be met, solar powered, bio-inspired constructs can contribute to renewable energy resources to meet human energy needs. The central challenge is reversing the combustion process by efficient water oxidation and reductive synthesis of CO2 to fuels. Nature's catalysts direct these oxidation/reduction reactions along coordinates that have low activation barriers and almost no side reactions. In principle, these reactions can be driven by electricity provided by sustainable sources. In order to accomplish this, it will be necessary to switch nature's catalysts from their usual source of redox potential - electron/proton carrying redox species - to emf at appropriate electrical potentials. Taking a step in this direction, we have assembled a hybrid system in which a porphyrin-sensitized Grätzel-type nanoparticulate wide band gap semiconductor photoanode is used as an interface between emf and redox potential for the photochemical reformation of biomass to hydrogen.
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M3 - Conference contribution
AN - SCOPUS:77955634195
SN - 9780841269859
T3 - ACS National Meeting Book of Abstracts
BT - American Chemical Society - 235th National Meeting, Abstracts of Scientific Papers
Y2 - 6 April 2008 through 10 April 2008
ER -