An emulsion technique for the study of marginal glass formation in molecular liquids

D. R. MacFarlane, Charles Angell

Research output: Contribution to journalArticle

28 Citations (Scopus)

Abstract

An emulsion has been used to discourage crystallization and permit the observation of a glass transition in molecular liquids such as chlorobenzene which were not previously thought to be glass forming. Glass-forming abilities in such marginal cases appear to be correlated by an extension of the Cohen-Turnbull TB/Tm > 2 rule. Transparent, repeatedly vitrefiable, microemulsions have also been made.

Original languageEnglish (US)
Pages (from-to)1927-1930
Number of pages4
JournalJournal of Physical Chemistry
Volume86
Issue number11
StatePublished - 1982
Externally publishedYes

Fingerprint

Emulsions
emulsions
Glass
glass
Microemulsions
Liquids
liquids
Crystallization
Glass transition
chlorobenzenes
crystallization
chlorobenzene

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry

Cite this

An emulsion technique for the study of marginal glass formation in molecular liquids. / MacFarlane, D. R.; Angell, Charles.

In: Journal of Physical Chemistry, Vol. 86, No. 11, 1982, p. 1927-1930.

Research output: Contribution to journalArticle

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