TY - JOUR
T1 - A molecular beam optical Stark study of nickel monohydride, NiH
AU - Chen, Jinhai
AU - Steimle, Timothy
N1 - Funding Information:
This research has been supported by the National Science Foundation – Experimental Physical Chemistry (Grant No. 0646473). The authors would like to thank Prof. Colan Linton (U. of New Brunswick) for his valuable comments.
PY - 2008/5/20
Y1 - 2008/5/20
N2 - The optical Stark effect in the B2Δ5/2 ← X2Δ5/2(1-0)Qe/f(5/2) and Pe/f(7/2) lines of nickel monohydride, 58NiH, was recorded and analyzed to produce values for the permanent electric dipole moment, μ, of 2.44 ± 0.02 D and 0.36 ± 0.02 D for the X2Δ5/2 and B2Δ5/2 states, respectively. The values are in agreement with the previously determined values [J.A. Gray, S.F. Rice, R.W. Field, J. Chem. Phys. 82 (1985) 4717] and with the experimental error approximately a factor of five smaller. A comparison with theoretical predictions and other first-row transition metal monohydrides is given.
AB - The optical Stark effect in the B2Δ5/2 ← X2Δ5/2(1-0)Qe/f(5/2) and Pe/f(7/2) lines of nickel monohydride, 58NiH, was recorded and analyzed to produce values for the permanent electric dipole moment, μ, of 2.44 ± 0.02 D and 0.36 ± 0.02 D for the X2Δ5/2 and B2Δ5/2 states, respectively. The values are in agreement with the previously determined values [J.A. Gray, S.F. Rice, R.W. Field, J. Chem. Phys. 82 (1985) 4717] and with the experimental error approximately a factor of five smaller. A comparison with theoretical predictions and other first-row transition metal monohydrides is given.
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U2 - 10.1016/j.cplett.2008.03.056
DO - 10.1016/j.cplett.2008.03.056
M3 - Article
AN - SCOPUS:43549085006
SN - 0009-2614
VL - 457
SP - 23
EP - 25
JO - Chemical Physics Letters
JF - Chemical Physics Letters
IS - 1-3
ER -