A molecular beam optical Stark study of nickel monohydride, NiH

Jinhai Chen, Timothy Steimle

Research output: Contribution to journalArticlepeer-review

5 Scopus citations

Abstract

The optical Stark effect in the B2Δ5/2 ← X2Δ5/2(1-0)Qe/f(5/2) and Pe/f(7/2) lines of nickel monohydride, 58NiH, was recorded and analyzed to produce values for the permanent electric dipole moment, μ, of 2.44 ± 0.02 D and 0.36 ± 0.02 D for the X2Δ5/2 and B2Δ5/2 states, respectively. The values are in agreement with the previously determined values [J.A. Gray, S.F. Rice, R.W. Field, J. Chem. Phys. 82 (1985) 4717] and with the experimental error approximately a factor of five smaller. A comparison with theoretical predictions and other first-row transition metal monohydrides is given.

Original languageEnglish (US)
Pages (from-to)23-25
Number of pages3
JournalChemical Physics Letters
Volume457
Issue number1-3
DOIs
StatePublished - May 20 2008

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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