Volatile and organic compositions of sedimentary rocks in Yellowknife Bay, Gale Crater, Mars

D. W. Ming, P. D. Archer, D. P. Glavin, J. L. Eigenbrode, H. B. Franz, B. Sutter, A. E. Brunner, J. C. Stern, C. Freissinet, A. C. McAdam, P. R. Mahaffy, M. Cabane, P. Coll, J. L. Campbell, S. K. Atreya, P. B. Niles, James Bell, D. L. Bish, W. B. Brinckerhoff, A. Buch & 37 others P. G. Conrad, D. J. Des Marais, B. L. Ehlmann, A. G. Fairén, K. Farley, G. J. Flesch, P. Francois, R. Gellert, J. A. Grant, J. P. Grotzinger, S. Gupta, K. E. Herkenhoff, J. A. Hurowitz, L. A. Leshin, K. W. Lewis, S. M. McLennan, K. E. Miller, J. Moersch, R. V. Morris, R. Navarro-González, A. A. Pavlov, G. M. Perrett, I. Pradler, S. W. Squyres, R. E. Summons, A. Steele, E. M. Stolper, D. Y. Sumner, C. Szopa, S. Teinturier, M. G. Trainer, A. H. Treiman, D. T. Vaniman, A. R. Vasavada, C. R. Webster, J. J. Wray, R. A. Yingst

Research output: Contribution to journalArticle

211 Citations (Scopus)

Abstract

H2O, CO2, SO2, O2, H 2, H2S, HCl, chlorinated hydrocarbons, NO, and other trace gases were evolved during pyrolysis of two mudstone samples acquired by the Curiosity rover at Yellowknife Bay within Gale crater, Mars. H 2O/OH-bearing phases included 2:1 phyllosilicate(s), bassanite, akaganeite, and amorphous materials. Thermal decomposition of carbonates and combustion of organic materials are candidate sources for the CO2. Concurrent evolution of O2 and chlorinated hydrocarbons suggests the presence of oxychlorine phase(s). Sulfides are likely sources for sulfur-bearing species. Higher abundances of chlorinated hydrocarbons in the mudstone compared with Rocknest windblown materials previously analyzed by Curiosity suggest that indigenous martian or meteoritic organic carbon sources may be preserved in the mudstone; however, the carbon source for the chlorinated hydrocarbons is not definitively of martian origin.

Original languageEnglish (US)
Article number1245267
JournalScience
Volume343
Issue number6169
DOIs
StatePublished - 2014

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Chlorinated Hydrocarbons
Mars
Exploratory Behavior
Carbon
Carbonates
Sulfides
Sulfur
Hot Temperature
Gases

ASJC Scopus subject areas

  • General
  • Medicine(all)

Cite this

Ming, D. W., Archer, P. D., Glavin, D. P., Eigenbrode, J. L., Franz, H. B., Sutter, B., ... Yingst, R. A. (2014). Volatile and organic compositions of sedimentary rocks in Yellowknife Bay, Gale Crater, Mars. Science, 343(6169), [1245267]. https://doi.org/10.1126/science.1245267

Volatile and organic compositions of sedimentary rocks in Yellowknife Bay, Gale Crater, Mars. / Ming, D. W.; Archer, P. D.; Glavin, D. P.; Eigenbrode, J. L.; Franz, H. B.; Sutter, B.; Brunner, A. E.; Stern, J. C.; Freissinet, C.; McAdam, A. C.; Mahaffy, P. R.; Cabane, M.; Coll, P.; Campbell, J. L.; Atreya, S. K.; Niles, P. B.; Bell, James; Bish, D. L.; Brinckerhoff, W. B.; Buch, A.; Conrad, P. G.; Des Marais, D. J.; Ehlmann, B. L.; Fairén, A. G.; Farley, K.; Flesch, G. J.; Francois, P.; Gellert, R.; Grant, J. A.; Grotzinger, J. P.; Gupta, S.; Herkenhoff, K. E.; Hurowitz, J. A.; Leshin, L. A.; Lewis, K. W.; McLennan, S. M.; Miller, K. E.; Moersch, J.; Morris, R. V.; Navarro-González, R.; Pavlov, A. A.; Perrett, G. M.; Pradler, I.; Squyres, S. W.; Summons, R. E.; Steele, A.; Stolper, E. M.; Sumner, D. Y.; Szopa, C.; Teinturier, S.; Trainer, M. G.; Treiman, A. H.; Vaniman, D. T.; Vasavada, A. R.; Webster, C. R.; Wray, J. J.; Yingst, R. A.

In: Science, Vol. 343, No. 6169, 1245267, 2014.

Research output: Contribution to journalArticle

Ming, DW, Archer, PD, Glavin, DP, Eigenbrode, JL, Franz, HB, Sutter, B, Brunner, AE, Stern, JC, Freissinet, C, McAdam, AC, Mahaffy, PR, Cabane, M, Coll, P, Campbell, JL, Atreya, SK, Niles, PB, Bell, J, Bish, DL, Brinckerhoff, WB, Buch, A, Conrad, PG, Des Marais, DJ, Ehlmann, BL, Fairén, AG, Farley, K, Flesch, GJ, Francois, P, Gellert, R, Grant, JA, Grotzinger, JP, Gupta, S, Herkenhoff, KE, Hurowitz, JA, Leshin, LA, Lewis, KW, McLennan, SM, Miller, KE, Moersch, J, Morris, RV, Navarro-González, R, Pavlov, AA, Perrett, GM, Pradler, I, Squyres, SW, Summons, RE, Steele, A, Stolper, EM, Sumner, DY, Szopa, C, Teinturier, S, Trainer, MG, Treiman, AH, Vaniman, DT, Vasavada, AR, Webster, CR, Wray, JJ & Yingst, RA 2014, 'Volatile and organic compositions of sedimentary rocks in Yellowknife Bay, Gale Crater, Mars', Science, vol. 343, no. 6169, 1245267. https://doi.org/10.1126/science.1245267
Ming DW, Archer PD, Glavin DP, Eigenbrode JL, Franz HB, Sutter B et al. Volatile and organic compositions of sedimentary rocks in Yellowknife Bay, Gale Crater, Mars. Science. 2014;343(6169). 1245267. https://doi.org/10.1126/science.1245267
Ming, D. W. ; Archer, P. D. ; Glavin, D. P. ; Eigenbrode, J. L. ; Franz, H. B. ; Sutter, B. ; Brunner, A. E. ; Stern, J. C. ; Freissinet, C. ; McAdam, A. C. ; Mahaffy, P. R. ; Cabane, M. ; Coll, P. ; Campbell, J. L. ; Atreya, S. K. ; Niles, P. B. ; Bell, James ; Bish, D. L. ; Brinckerhoff, W. B. ; Buch, A. ; Conrad, P. G. ; Des Marais, D. J. ; Ehlmann, B. L. ; Fairén, A. G. ; Farley, K. ; Flesch, G. J. ; Francois, P. ; Gellert, R. ; Grant, J. A. ; Grotzinger, J. P. ; Gupta, S. ; Herkenhoff, K. E. ; Hurowitz, J. A. ; Leshin, L. A. ; Lewis, K. W. ; McLennan, S. M. ; Miller, K. E. ; Moersch, J. ; Morris, R. V. ; Navarro-González, R. ; Pavlov, A. A. ; Perrett, G. M. ; Pradler, I. ; Squyres, S. W. ; Summons, R. E. ; Steele, A. ; Stolper, E. M. ; Sumner, D. Y. ; Szopa, C. ; Teinturier, S. ; Trainer, M. G. ; Treiman, A. H. ; Vaniman, D. T. ; Vasavada, A. R. ; Webster, C. R. ; Wray, J. J. ; Yingst, R. A. / Volatile and organic compositions of sedimentary rocks in Yellowknife Bay, Gale Crater, Mars. In: Science. 2014 ; Vol. 343, No. 6169.
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abstract = "H2O, CO2, SO2, O2, H 2, H2S, HCl, chlorinated hydrocarbons, NO, and other trace gases were evolved during pyrolysis of two mudstone samples acquired by the Curiosity rover at Yellowknife Bay within Gale crater, Mars. H 2O/OH-bearing phases included 2:1 phyllosilicate(s), bassanite, akaganeite, and amorphous materials. Thermal decomposition of carbonates and combustion of organic materials are candidate sources for the CO2. Concurrent evolution of O2 and chlorinated hydrocarbons suggests the presence of oxychlorine phase(s). Sulfides are likely sources for sulfur-bearing species. Higher abundances of chlorinated hydrocarbons in the mudstone compared with Rocknest windblown materials previously analyzed by Curiosity suggest that indigenous martian or meteoritic organic carbon sources may be preserved in the mudstone; however, the carbon source for the chlorinated hydrocarbons is not definitively of martian origin.",
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T1 - Volatile and organic compositions of sedimentary rocks in Yellowknife Bay, Gale Crater, Mars

AU - Ming, D. W.

AU - Archer, P. D.

AU - Glavin, D. P.

AU - Eigenbrode, J. L.

AU - Franz, H. B.

AU - Sutter, B.

AU - Brunner, A. E.

AU - Stern, J. C.

AU - Freissinet, C.

AU - McAdam, A. C.

AU - Mahaffy, P. R.

AU - Cabane, M.

AU - Coll, P.

AU - Campbell, J. L.

AU - Atreya, S. K.

AU - Niles, P. B.

AU - Bell, James

AU - Bish, D. L.

AU - Brinckerhoff, W. B.

AU - Buch, A.

AU - Conrad, P. G.

AU - Des Marais, D. J.

AU - Ehlmann, B. L.

AU - Fairén, A. G.

AU - Farley, K.

AU - Flesch, G. J.

AU - Francois, P.

AU - Gellert, R.

AU - Grant, J. A.

AU - Grotzinger, J. P.

AU - Gupta, S.

AU - Herkenhoff, K. E.

AU - Hurowitz, J. A.

AU - Leshin, L. A.

AU - Lewis, K. W.

AU - McLennan, S. M.

AU - Miller, K. E.

AU - Moersch, J.

AU - Morris, R. V.

AU - Navarro-González, R.

AU - Pavlov, A. A.

AU - Perrett, G. M.

AU - Pradler, I.

AU - Squyres, S. W.

AU - Summons, R. E.

AU - Steele, A.

AU - Stolper, E. M.

AU - Sumner, D. Y.

AU - Szopa, C.

AU - Teinturier, S.

AU - Trainer, M. G.

AU - Treiman, A. H.

AU - Vaniman, D. T.

AU - Vasavada, A. R.

AU - Webster, C. R.

AU - Wray, J. J.

AU - Yingst, R. A.

PY - 2014

Y1 - 2014

N2 - H2O, CO2, SO2, O2, H 2, H2S, HCl, chlorinated hydrocarbons, NO, and other trace gases were evolved during pyrolysis of two mudstone samples acquired by the Curiosity rover at Yellowknife Bay within Gale crater, Mars. H 2O/OH-bearing phases included 2:1 phyllosilicate(s), bassanite, akaganeite, and amorphous materials. Thermal decomposition of carbonates and combustion of organic materials are candidate sources for the CO2. Concurrent evolution of O2 and chlorinated hydrocarbons suggests the presence of oxychlorine phase(s). Sulfides are likely sources for sulfur-bearing species. Higher abundances of chlorinated hydrocarbons in the mudstone compared with Rocknest windblown materials previously analyzed by Curiosity suggest that indigenous martian or meteoritic organic carbon sources may be preserved in the mudstone; however, the carbon source for the chlorinated hydrocarbons is not definitively of martian origin.

AB - H2O, CO2, SO2, O2, H 2, H2S, HCl, chlorinated hydrocarbons, NO, and other trace gases were evolved during pyrolysis of two mudstone samples acquired by the Curiosity rover at Yellowknife Bay within Gale crater, Mars. H 2O/OH-bearing phases included 2:1 phyllosilicate(s), bassanite, akaganeite, and amorphous materials. Thermal decomposition of carbonates and combustion of organic materials are candidate sources for the CO2. Concurrent evolution of O2 and chlorinated hydrocarbons suggests the presence of oxychlorine phase(s). Sulfides are likely sources for sulfur-bearing species. Higher abundances of chlorinated hydrocarbons in the mudstone compared with Rocknest windblown materials previously analyzed by Curiosity suggest that indigenous martian or meteoritic organic carbon sources may be preserved in the mudstone; however, the carbon source for the chlorinated hydrocarbons is not definitively of martian origin.

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