Understanding the distribution of chlorine in perovskite solar cells via x-ray fluorescence microscopyl

Yanqi Luo, Shany Gamliel, Sally Nijem, Sigalit Aharon, Martin Holt, Benjamin Stripe, Volker Rose, Mariana Bertoni, Lioz Etgar, David P. Fenning

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

Spatial heterogeneities in the chemical makeup of thin film photovoltaic devices are pivotal in determining device efficiency. In this study, the presence of chlorine is identified in perovskite films synthesized with Cl-containing precursors by means of nanoprobe X-ray fluorescence (Nano-XRF). Additionally, a spatial variation in the Cl incorporation is observed within a given film, and the standard deviation of Cl: I ratio across the film is large. Using Nano-XRF, the Cl incorporation in methylammonium lead iodide perovskite films can be manipulated by precursor stoichiometry ratio.

Original languageEnglish (US)
Title of host publication2016 IEEE 43rd Photovoltaic Specialists Conference, PVSC 2016
PublisherInstitute of Electrical and Electronics Engineers Inc.
Pages802-803
Number of pages2
Volume2016-November
ISBN (Electronic)9781509027248
DOIs
StatePublished - Nov 18 2016
Event43rd IEEE Photovoltaic Specialists Conference, PVSC 2016 - Portland, United States
Duration: Jun 5 2016Jun 10 2016

Other

Other43rd IEEE Photovoltaic Specialists Conference, PVSC 2016
CountryUnited States
CityPortland
Period6/5/166/10/16

Fingerprint

Chlorine
Fluorescence
Nanoprobes
X rays
Perovskite
Stoichiometry
Lead
Thin films
Perovskite solar cells

Keywords

  • Cl containing precursors
  • elemental distribution
  • nano-XRF
  • perovskite solar cells
  • synchrotron based technique

ASJC Scopus subject areas

  • Control and Systems Engineering
  • Industrial and Manufacturing Engineering
  • Electrical and Electronic Engineering

Cite this

Luo, Y., Gamliel, S., Nijem, S., Aharon, S., Holt, M., Stripe, B., ... Fenning, D. P. (2016). Understanding the distribution of chlorine in perovskite solar cells via x-ray fluorescence microscopyl. In 2016 IEEE 43rd Photovoltaic Specialists Conference, PVSC 2016 (Vol. 2016-November, pp. 802-803). [7749715] Institute of Electrical and Electronics Engineers Inc.. https://doi.org/10.1109/PVSC.2016.7749715

Understanding the distribution of chlorine in perovskite solar cells via x-ray fluorescence microscopyl. / Luo, Yanqi; Gamliel, Shany; Nijem, Sally; Aharon, Sigalit; Holt, Martin; Stripe, Benjamin; Rose, Volker; Bertoni, Mariana; Etgar, Lioz; Fenning, David P.

2016 IEEE 43rd Photovoltaic Specialists Conference, PVSC 2016. Vol. 2016-November Institute of Electrical and Electronics Engineers Inc., 2016. p. 802-803 7749715.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Luo, Y, Gamliel, S, Nijem, S, Aharon, S, Holt, M, Stripe, B, Rose, V, Bertoni, M, Etgar, L & Fenning, DP 2016, Understanding the distribution of chlorine in perovskite solar cells via x-ray fluorescence microscopyl. in 2016 IEEE 43rd Photovoltaic Specialists Conference, PVSC 2016. vol. 2016-November, 7749715, Institute of Electrical and Electronics Engineers Inc., pp. 802-803, 43rd IEEE Photovoltaic Specialists Conference, PVSC 2016, Portland, United States, 6/5/16. https://doi.org/10.1109/PVSC.2016.7749715
Luo Y, Gamliel S, Nijem S, Aharon S, Holt M, Stripe B et al. Understanding the distribution of chlorine in perovskite solar cells via x-ray fluorescence microscopyl. In 2016 IEEE 43rd Photovoltaic Specialists Conference, PVSC 2016. Vol. 2016-November. Institute of Electrical and Electronics Engineers Inc. 2016. p. 802-803. 7749715 https://doi.org/10.1109/PVSC.2016.7749715
Luo, Yanqi ; Gamliel, Shany ; Nijem, Sally ; Aharon, Sigalit ; Holt, Martin ; Stripe, Benjamin ; Rose, Volker ; Bertoni, Mariana ; Etgar, Lioz ; Fenning, David P. / Understanding the distribution of chlorine in perovskite solar cells via x-ray fluorescence microscopyl. 2016 IEEE 43rd Photovoltaic Specialists Conference, PVSC 2016. Vol. 2016-November Institute of Electrical and Electronics Engineers Inc., 2016. pp. 802-803
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