Understanding and tuning the hydrogen evolution reaction on Pt-covered tungsten carbide cathodes

Houlong Zhuang, Alexander J. Tkalych, Emily A. Carter

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

Understanding and tailoring the interactions between hydrogen (H) atoms and catalytic surfaces is critical to developing electro-catalysts with less platinum (Pt). Tungsten carbide (WC) is a possible valence isoelectronic substitute for Pt. Using first-principles quantum mechanics calculations, we systematically investigate H binding to WC(0001) and Pt(111) surfaces. Moreover, inspired by recent experiments on hybrid monolayer-Pt/WC catalysts, we study H adsorption on these hybrid surfaces. We consider both W and C terminations and vary the number of Pt layers. We predict that the H binding energy (HBE) plateaus rapidly with the number of Pt layers and that a monolayer of Pt on a WC substrate has a similar HBE to that of pure Pt. This corroborates the experimental observation that the two systems exhibit similar electrochemical activities. Increasing the number of Pt layers leads to a slight increase in the HBE and a projected decrease in catalytic activity. Through various electronic structure analyses, we show that the similarity in activities is due to an intrinsic alteration of the character of the Pt/WC surface rather than a similarity to the pure Pt surface. Our findings provide guidance for tuning parameters that affect catalytic activity by controlling WC surface termination and Pt overlayer thickness.

Original languageEnglish (US)
Pages (from-to)F629-F636
JournalJournal of the Electrochemical Society
Volume163
Issue number7
DOIs
StatePublished - Jan 1 2016
Externally publishedYes

Fingerprint

Tungsten carbide
Platinum
Hydrogen
Cathodes
Tuning
Binding energy
tungsten carbide
Monolayers
Catalyst activity
Catalysts
Electronic guidance systems
Quantum theory
Electronic structure

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Renewable Energy, Sustainability and the Environment
  • Surfaces, Coatings and Films
  • Electrochemistry
  • Materials Chemistry

Cite this

Understanding and tuning the hydrogen evolution reaction on Pt-covered tungsten carbide cathodes. / Zhuang, Houlong; Tkalych, Alexander J.; Carter, Emily A.

In: Journal of the Electrochemical Society, Vol. 163, No. 7, 01.01.2016, p. F629-F636.

Research output: Contribution to journalArticle

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