UiO-66 MOF and Poly(vinyl cinnamate) Nanofiber Composite Membranes Synthesized by a Facile Three-Stage Process

Mitchell R. Armstrong; Korinthia Y Yuriar Arredondo; Chao Yuan Liu; Joshua E. Stevens; Alexandre Mayhob; Bohan Shan; Sethuraman Senthilnathan; Christopher J. Balzer; Bin Mu

doi:10.1021/acs.iecr.5b03334

UiO-66 MOF and Poly(vinyl cinnamate) Nanofiber Composite Membranes Synthesized by a Facile Three-Stage Process

Mitchell R. Armstrong, Korinthia Y Yuriar Arredondo, Chao Yuan Liu, Joshua E. Stevens, Alexandre Mayhob, Bohan Shan, Sethuraman Senthilnathan, Christopher J. Balzer, Bin Mu

Research output: Contribution to journal › Article › peer-review

47 Scopus citations

Abstract

Electrospun poly(vinyl cinnamate) (PVCi) nanofibers were cross-linked for varying times to study the impact it has on fiber stability at elevated temperatures and in dimethylformamide solutions. UiO-66 impregnated PVCi was cross-linked, and secondary growth of UiO-66 crystals was performed. The impact of temperature and number of growths was analyzed through powder X-ray diffraction, scanning electron microscopy, and Fourier transform infrared spectroscopy. A membrane that underwent three growth cycles at 100 °C was further characterized for potential uses as a gas membrane through inert gas permeation studies and nitrogen porosimetry.

Original language	English (US)
Pages (from-to)	12386-12392
Number of pages	7
Journal	Industrial and Engineering Chemistry Research
Volume	54
Issue number	49
DOIs	https://doi.org/10.1021/acs.iecr.5b03334
State	Published - Dec 16 2015

ASJC Scopus subject areas

General Chemical Engineering
General Chemistry
Industrial and Manufacturing Engineering

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title = "UiO-66 MOF and Poly(vinyl cinnamate) Nanofiber Composite Membranes Synthesized by a Facile Three-Stage Process",

abstract = "Electrospun poly(vinyl cinnamate) (PVCi) nanofibers were cross-linked for varying times to study the impact it has on fiber stability at elevated temperatures and in dimethylformamide solutions. UiO-66 impregnated PVCi was cross-linked, and secondary growth of UiO-66 crystals was performed. The impact of temperature and number of growths was analyzed through powder X-ray diffraction, scanning electron microscopy, and Fourier transform infrared spectroscopy. A membrane that underwent three growth cycles at 100 °C was further characterized for potential uses as a gas membrane through inert gas permeation studies and nitrogen porosimetry.",

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doi = "10.1021/acs.iecr.5b03334",

language = "English (US)",

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journal = "Industrial and Engineering Chemistry Research",

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T1 - UiO-66 MOF and Poly(vinyl cinnamate) Nanofiber Composite Membranes Synthesized by a Facile Three-Stage Process

AU - Armstrong, Mitchell R.

AU - Arredondo, Korinthia Y Yuriar

AU - Liu, Chao Yuan

AU - Stevens, Joshua E.

AU - Mayhob, Alexandre

AU - Shan, Bohan

AU - Senthilnathan, Sethuraman

AU - Balzer, Christopher J.

AU - Mu, Bin

PY - 2015/12/16

Y1 - 2015/12/16

N2 - Electrospun poly(vinyl cinnamate) (PVCi) nanofibers were cross-linked for varying times to study the impact it has on fiber stability at elevated temperatures and in dimethylformamide solutions. UiO-66 impregnated PVCi was cross-linked, and secondary growth of UiO-66 crystals was performed. The impact of temperature and number of growths was analyzed through powder X-ray diffraction, scanning electron microscopy, and Fourier transform infrared spectroscopy. A membrane that underwent three growth cycles at 100 °C was further characterized for potential uses as a gas membrane through inert gas permeation studies and nitrogen porosimetry.

AB - Electrospun poly(vinyl cinnamate) (PVCi) nanofibers were cross-linked for varying times to study the impact it has on fiber stability at elevated temperatures and in dimethylformamide solutions. UiO-66 impregnated PVCi was cross-linked, and secondary growth of UiO-66 crystals was performed. The impact of temperature and number of growths was analyzed through powder X-ray diffraction, scanning electron microscopy, and Fourier transform infrared spectroscopy. A membrane that underwent three growth cycles at 100 °C was further characterized for potential uses as a gas membrane through inert gas permeation studies and nitrogen porosimetry.

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JO - Industrial and Engineering Chemistry Research

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ER -

UiO-66 MOF and Poly(vinyl cinnamate) Nanofiber Composite Membranes Synthesized by a Facile Three-Stage Process

Abstract

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