UiO-66 MOF and Poly(vinyl cinnamate) Nanofiber Composite Membranes Synthesized by a Facile Three-Stage Process

Mitchell R. Armstrong, Korinthia Y Yuriar Arredondo, Chao Yuan Liu, Joshua E. Stevens, Alexandre Mayhob, Bohan Shan, Sethuraman Senthilnathan, Christopher J. Balzer, Bin Mu

Research output: Contribution to journalArticle

26 Citations (Scopus)

Abstract

Electrospun poly(vinyl cinnamate) (PVCi) nanofibers were cross-linked for varying times to study the impact it has on fiber stability at elevated temperatures and in dimethylformamide solutions. UiO-66 impregnated PVCi was cross-linked, and secondary growth of UiO-66 crystals was performed. The impact of temperature and number of growths was analyzed through powder X-ray diffraction, scanning electron microscopy, and Fourier transform infrared spectroscopy. A membrane that underwent three growth cycles at 100 °C was further characterized for potential uses as a gas membrane through inert gas permeation studies and nitrogen porosimetry.

Original languageEnglish (US)
Pages (from-to)12386-12392
Number of pages7
JournalIndustrial and Engineering Chemistry Research
Volume54
Issue number49
DOIs
StatePublished - Dec 16 2015

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Cinnamates
Composite membranes
Nanofibers
Membranes
Noble Gases
Dimethylformamide
Inert gases
Permeation
X ray powder diffraction
Fourier transform infrared spectroscopy
Nitrogen
Gases
Temperature
Crystals
Scanning electron microscopy
Fibers

ASJC Scopus subject areas

  • Chemical Engineering(all)
  • Chemistry(all)
  • Industrial and Manufacturing Engineering

Cite this

UiO-66 MOF and Poly(vinyl cinnamate) Nanofiber Composite Membranes Synthesized by a Facile Three-Stage Process. / Armstrong, Mitchell R.; Arredondo, Korinthia Y Yuriar; Liu, Chao Yuan; Stevens, Joshua E.; Mayhob, Alexandre; Shan, Bohan; Senthilnathan, Sethuraman; Balzer, Christopher J.; Mu, Bin.

In: Industrial and Engineering Chemistry Research, Vol. 54, No. 49, 16.12.2015, p. 12386-12392.

Research output: Contribution to journalArticle

Armstrong, MR, Arredondo, KYY, Liu, CY, Stevens, JE, Mayhob, A, Shan, B, Senthilnathan, S, Balzer, CJ & Mu, B 2015, 'UiO-66 MOF and Poly(vinyl cinnamate) Nanofiber Composite Membranes Synthesized by a Facile Three-Stage Process', Industrial and Engineering Chemistry Research, vol. 54, no. 49, pp. 12386-12392. https://doi.org/10.1021/acs.iecr.5b03334
Armstrong, Mitchell R. ; Arredondo, Korinthia Y Yuriar ; Liu, Chao Yuan ; Stevens, Joshua E. ; Mayhob, Alexandre ; Shan, Bohan ; Senthilnathan, Sethuraman ; Balzer, Christopher J. ; Mu, Bin. / UiO-66 MOF and Poly(vinyl cinnamate) Nanofiber Composite Membranes Synthesized by a Facile Three-Stage Process. In: Industrial and Engineering Chemistry Research. 2015 ; Vol. 54, No. 49. pp. 12386-12392.
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