Trends in structure and thermodynamic properties of normal rare earth carbonates and rare earth hydroxycarbonates

Paul Kim; Andre Anderko; Alexandra Navrotsky; Richard E. Riman

doi:10.3390/min8030106

Trends in structure and thermodynamic properties of normal rare earth carbonates and rare earth hydroxycarbonates

Paul Kim, Andre Anderko, Alexandra Navrotsky, Richard E. Riman

Research output: Contribution to journal › Review article › peer-review

58 Scopus citations

Abstract

A general overview of the trends in structural and thermodynamic properties that have been identified within the hydrated normal rare earth carbonates and the rare earth hydroxycarbonates is presented. Based upon available literature, we demonstrate the trends in crystallographic unit cell parameters, thermal stability, aqueous solubility, and thermochemical properties. These trends can be attributed to both the unique chemistry and strong similarity of the rare earth elements. There are also inconsistent trends that signal research needs to better understand the structure–energy relationships of the rare earth carbonates.

Original language	English (US)
Article number	106
Journal	Minerals
Volume	8
Issue number	3
DOIs	https://doi.org/10.3390/min8030106
State	Published - Mar 7 2018
Externally published	Yes

Keywords

Hydroxycarbonates
Normal carbonates
Property correlations
Rare-earth carbonates
Thermodynamic properties

ASJC Scopus subject areas

Geotechnical Engineering and Engineering Geology
Geology

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10.3390/min8030106

Cite this

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title = "Trends in structure and thermodynamic properties of normal rare earth carbonates and rare earth hydroxycarbonates",

abstract = "A general overview of the trends in structural and thermodynamic properties that have been identified within the hydrated normal rare earth carbonates and the rare earth hydroxycarbonates is presented. Based upon available literature, we demonstrate the trends in crystallographic unit cell parameters, thermal stability, aqueous solubility, and thermochemical properties. These trends can be attributed to both the unique chemistry and strong similarity of the rare earth elements. There are also inconsistent trends that signal research needs to better understand the structure–energy relationships of the rare earth carbonates.",

keywords = "Hydroxycarbonates, Normal carbonates, Property correlations, Rare-earth carbonates, Thermodynamic properties",

author = "Paul Kim and Andre Anderko and Alexandra Navrotsky and Riman, {Richard E.}",

note = "Funding Information: Acknowledgments: Funding from the Critical Materials Institute, an Energy Innovation Hub funded by the U.S. Department of Energy, Office of Energy Efficiency and Renewable Energy, Advanced Manufacturing Office (AMES LABORATORY–SC-13-394) is gratefully acknowledged. Publisher Copyright: {\textcopyright} 2018 by the authors. Licensee MDPI, Basel, Switzerland.",

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T1 - Trends in structure and thermodynamic properties of normal rare earth carbonates and rare earth hydroxycarbonates

AU - Kim, Paul

AU - Anderko, Andre

AU - Navrotsky, Alexandra

AU - Riman, Richard E.

N1 - Funding Information: Acknowledgments: Funding from the Critical Materials Institute, an Energy Innovation Hub funded by the U.S. Department of Energy, Office of Energy Efficiency and Renewable Energy, Advanced Manufacturing Office (AMES LABORATORY–SC-13-394) is gratefully acknowledged. Publisher Copyright: © 2018 by the authors. Licensee MDPI, Basel, Switzerland.

PY - 2018/3/7

Y1 - 2018/3/7

N2 - A general overview of the trends in structural and thermodynamic properties that have been identified within the hydrated normal rare earth carbonates and the rare earth hydroxycarbonates is presented. Based upon available literature, we demonstrate the trends in crystallographic unit cell parameters, thermal stability, aqueous solubility, and thermochemical properties. These trends can be attributed to both the unique chemistry and strong similarity of the rare earth elements. There are also inconsistent trends that signal research needs to better understand the structure–energy relationships of the rare earth carbonates.

AB - A general overview of the trends in structural and thermodynamic properties that have been identified within the hydrated normal rare earth carbonates and the rare earth hydroxycarbonates is presented. Based upon available literature, we demonstrate the trends in crystallographic unit cell parameters, thermal stability, aqueous solubility, and thermochemical properties. These trends can be attributed to both the unique chemistry and strong similarity of the rare earth elements. There are also inconsistent trends that signal research needs to better understand the structure–energy relationships of the rare earth carbonates.

KW - Hydroxycarbonates

KW - Normal carbonates

KW - Property correlations

KW - Rare-earth carbonates

KW - Thermodynamic properties

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DO - 10.3390/min8030106

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JF - Minerals

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Trends in structure and thermodynamic properties of normal rare earth carbonates and rare earth hydroxycarbonates

Abstract

Keywords

ASJC Scopus subject areas

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