TY - JOUR
T1 - TRENDS AND SYSTEMATICS IN MINERAL THERMODYNAMICS.
AU - Navrotsky, Alexandra
N1 - Copyright:
Copyright 2017 Elsevier B.V., All rights reserved.
PY - 1982
Y1 - 1982
N2 - The stability of complex oxide and silicate phases can be understood in terms of equally important contributions of energy and entropy effects. The change in coordination number at high pressure in silicates has a profound effect on thermodynamic properties. Properties of spinel solid solutions can be systematized using a refined cation distribution model, while those of solid solutions involving no cation redistribution can be correlated with the volume mismatch of the end-members for a wide variety of structures and compositions. Ordering and exsolution in complex solid solutions is an important feature.
AB - The stability of complex oxide and silicate phases can be understood in terms of equally important contributions of energy and entropy effects. The change in coordination number at high pressure in silicates has a profound effect on thermodynamic properties. Properties of spinel solid solutions can be systematized using a refined cation distribution model, while those of solid solutions involving no cation redistribution can be correlated with the volume mismatch of the end-members for a wide variety of structures and compositions. Ordering and exsolution in complex solid solutions is an important feature.
UR - http://www.scopus.com/inward/record.url?scp=0020203359&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0020203359&partnerID=8YFLogxK
U2 - 10.1002/bbpc.198200005
DO - 10.1002/bbpc.198200005
M3 - Article
AN - SCOPUS:0020203359
VL - 86
SP - 994
EP - 1001
JO - Berichte der Bunsengesellschaft/Physical Chemistry Chemical Physics
JF - Berichte der Bunsengesellschaft/Physical Chemistry Chemical Physics
SN - 0005-9021
IS - 11
ER -