Abstract
The fundamental problem of how a nonlinear coupling of the solute to the solvent affects time-resolved spectral line shapes and observable spectral moments is addressed. In particular, an exact solution for the time-dependent time-resolved fluorescence (TRF) line shape is given. This solution allows to analyze approximations commonly adopted in the theoretical analysis of transient spectra.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 8933-8941 |
| Number of pages | 9 |
| Journal | Journal of Chemical Physics |
| Volume | 115 |
| Issue number | 19 |
| DOIs | |
| State | Published - Nov 15 2001 |
ASJC Scopus subject areas
- Physics and Astronomy(all)
- Physical and Theoretical Chemistry