Time-resolved flash spectroscopic investigations of the reactions of singlet arylhalocarbenes

I. R. Gould; N. J. Turbo; J. Butcher; C. Doubleday; N. P. Hacker; G. F. Lehr; R. A. Moss; D. P. Cox; W. Guo; R. C. Munjal; L. A. Perez; M. Fedorynski

doi:10.1016/S0040-4020(01)96399-9

Time-resolved flash spectroscopic investigations of the reactions of singlet arylhalocarbenes

I. R. Gould, N. J. Turbo, J. Butcher, C. Doubleday, N. P. Hacker, G. F. Lehr, R. A. Moss, D. P. Cox, W. Guo, R. C. Munjal, L. A. Perez, M. Fedorynski

Research output: Contribution to journal › Article › peer-review

87 Scopus citations

Abstract

The results of time-resolved laser flash spectrometric studies of singlet arylhalocarbenes are reviewed. In particular, the absolute rate constants for reactions of phenylchlorocarbene and related carbenes with alkenes are summarized and systematized. The experiments described provide the basis for a detailed examination of carbenic reactivity-selectivity principles. The results of studies on the influence of temperature on the absolute rate constants for carbene reactions are consistent with the existence of transient carbene/alkene intermediates.

Original language	English (US)
Pages (from-to)	1587-1600
Number of pages	14
Journal	Tetrahedron
Volume	41
Issue number	8
DOIs	https://doi.org/10.1016/S0040-4020(01)96399-9
State	Published - 1985
Externally published	Yes

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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title = "Time-resolved flash spectroscopic investigations of the reactions of singlet arylhalocarbenes",

abstract = "The results of time-resolved laser flash spectrometric studies of singlet arylhalocarbenes are reviewed. In particular, the absolute rate constants for reactions of phenylchlorocarbene and related carbenes with alkenes are summarized and systematized. The experiments described provide the basis for a detailed examination of carbenic reactivity-selectivity principles. The results of studies on the influence of temperature on the absolute rate constants for carbene reactions are consistent with the existence of transient carbene/alkene intermediates.",

author = "Gould, {I. R.} and Turbo, {N. J.} and J. Butcher and C. Doubleday and Hacker, {N. P.} and Lehr, {G. F.} and Moss, {R. A.} and Cox, {D. P.} and W. Guo and Munjal, {R. C.} and Perez, {L. A.} and M. Fedorynski",

year = "1985",

doi = "10.1016/S0040-4020(01)96399-9",

language = "English (US)",

volume = "41",

pages = "1587--1600",

journal = "Tetrahedron",

issn = "0040-4020",

publisher = "Elsevier Limited",

number = "8",

}

TY - JOUR

T1 - Time-resolved flash spectroscopic investigations of the reactions of singlet arylhalocarbenes

AU - Gould, I. R.

AU - Turbo, N. J.

AU - Butcher, J.

AU - Doubleday, C.

AU - Hacker, N. P.

AU - Lehr, G. F.

AU - Moss, R. A.

AU - Cox, D. P.

AU - Guo, W.

AU - Munjal, R. C.

AU - Perez, L. A.

AU - Fedorynski, M.

PY - 1985

Y1 - 1985

N2 - The results of time-resolved laser flash spectrometric studies of singlet arylhalocarbenes are reviewed. In particular, the absolute rate constants for reactions of phenylchlorocarbene and related carbenes with alkenes are summarized and systematized. The experiments described provide the basis for a detailed examination of carbenic reactivity-selectivity principles. The results of studies on the influence of temperature on the absolute rate constants for carbene reactions are consistent with the existence of transient carbene/alkene intermediates.

AB - The results of time-resolved laser flash spectrometric studies of singlet arylhalocarbenes are reviewed. In particular, the absolute rate constants for reactions of phenylchlorocarbene and related carbenes with alkenes are summarized and systematized. The experiments described provide the basis for a detailed examination of carbenic reactivity-selectivity principles. The results of studies on the influence of temperature on the absolute rate constants for carbene reactions are consistent with the existence of transient carbene/alkene intermediates.

UR - http://www.scopus.com/inward/record.url?scp=0001524770&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0001524770&partnerID=8YFLogxK

U2 - 10.1016/S0040-4020(01)96399-9

DO - 10.1016/S0040-4020(01)96399-9

M3 - Article

AN - SCOPUS:0001524770

SN - 0040-4020

VL - 41

SP - 1587

EP - 1600

JO - Tetrahedron

JF - Tetrahedron

IS - 8

ER -

Time-resolved flash spectroscopic investigations of the reactions of singlet arylhalocarbenes

Abstract

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