Thermochemistry of Glasses in the Y2O3-Al 2O3-SiO2 System

Yahong Zhang, Alexandra Navrotsky

Research output: Contribution to journalArticlepeer-review

25 Scopus citations

Abstract

Enthalpies of drop solution in molten 2PbO-B2O3 at 1078 K were measured for glasses along the 2YAlO3-3SiO2 and 1/2Y3Al5O12-3SiO2 joins. The onset glass transition temperature increases slightly with increasing silica content and Y/Al. Enthalpies of mixing were calculated on the basis of amorphous end members. Strongly negative heats of mixing support the absence of miscibility gaps except possibly for very high silica content, consistent with experimental phase analyses, which indicate much narrower miscibility gaps compared with the phase diagrams calculated on the basis of previous data and the CALPHAD formalism.

Original languageEnglish (US)
Pages (from-to)1727-1732
Number of pages6
JournalJournal of the American Ceramic Society
Volume86
Issue number10
DOIs
StatePublished - Oct 2003
Externally publishedYes

ASJC Scopus subject areas

  • Ceramics and Composites
  • Materials Chemistry

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